CHEM1112 Lecture Notes - Lecture 11: Aldehyde, Ketone, Substituent

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Identify and name simple ketones and aldehydes
Screen clipping taken: 2/10/2017 3:42 PM
Suffix of -one
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Common name for ketones are substituent groups listed alphabetically + ketone
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Ketones
Screen clipping taken: 2/10/2017 3:43 PM
Suffix -al
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Aldehyde functional group is given the #1 numbering location and this number is NOT included
in name
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11.1
Monday, 2 October 2017
11:18 AM
11. Aldehydes and Ketones Page 1
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11. Aldehydes and Ketones Page 2
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Document Summary

Common name for ketones are substituent groups listed alphabetically + ketone. Aldehyde functional group is given the #1 numbering location and this number is not included in name: aldehydes and ketones page 1. Screen clipping taken: 2/10/2017 3:44 pm: aldehydes and ketones page 2. Predict the products of oxidation and reduction of aldehydes and ketones and give the reagents required to perform these reactions. Double bond - consists of one pi and sigma bond. Carbonyls exist on its own in aldehydes and ketones. Reduction with hydride and addition to carbonyl group. Type of nucleophile h- (h with lone pair) Reagents which are common sources of hydride (h-): lialh4, nabh4: aldehydes and ketones page 3. Reagents which are common sources of hydride (h-): lialh4, nabh4 e. g. nucleophilic addition reaction, reduction reaction. Double bond electrons shift to oxygen (intermediate product, alkoxide) work-up reaction to isolate the organic product - perform an addition of.