CHEM1003 Lecture Notes - Lecture 32: Staggered Conformation, Eclipsed Conformation, Newman Projection

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Lecture 32
Sunday, 29 May 2016
12:07 pm
Organic Chemistry (2)
Conformation around Alkanes - Rotation about Single Bonds:
Conformations - different arrangements of atoms in molecule that result from
rotation about a single bond
Rotations occur to achieve the most energetically stable conformations in a
molecule
Conformations are represented in 2 different ways
o Sawhorse representation
o Newman projection
o Staggered conformation - more favourable as molecules are furthest
apart
o Eclipsed conformation
Alkenes and Alkynes:
Alkenes - hydrocarbons that contain a carbon-carbon double bond [CnH2n]
o E.g.
Alkynes - hydrocarbons containing a carbon-carbon triple bond [CnH2n-2]
o E.g.
Structures of Alkenes:
One or more C=C bonds
Contain fewer hydrogen atoms per C atam than related alkenes
Referred to as unsaturated
Angle between carbon and hydrogen is larger - 121.7o
Rules for Naming Alkenes:
Select the longest continuous chain of carbon atoms that contains the double
bond
Root hydrocarbon name ends in -ene
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