CHEM 001 Lecture Notes - Lecture 7: Dmitri Mendeleev, Neon Sign, Incandescent Light Bulb

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skywildebeest596

7 Aug 2020

School

College of The Sequoias

Department

Chemistry (CHEM)

Course

CHEM 001

Professor

Rodriguez

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For argon atoms, there are three distinct groups of electrons in each atom whose energies of removal are in the ratio: 1:14:170. Shell model: the evidence for electrons existing at certain distances from the nucleus. Groups of electrons exist in concentric shells about the nucleus of the atom. Electrons that are most difficult to remove lie in the shell closest to the nucleus, and those more easy to remove lie in shells further from the nucleus. Simply represent regions about the nucleus where the electrons are most likely to be found. Only electrons contained in the outermost shell (valence shell) of an atom affect the chemical properties of an element. Maximum number of electrons per shell in atoms equation: 2n^2. There is no upper limit to n. The electron configuration of an atom indicates how its electrons are distributed. Electron configuration: the allocation of electrons to the various shells in an atom.

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CHEM 1430 LIGHT LAB SPRING 2018 A Danish physicist, Neils Bohr, a post-doctoral student in J. J. Thomson's lab and friend of Rutherford, took up the problem of electron arrangement within the atom. Bohr's breakthrough was recognizing Balmer's fixed emission wavelengths, when taken with Planck's Relationship, led to the conclusion the shells, like the radiation emitted, must be quantized (have set, specific energles). Bohr proposed the electrons circulated about the madeus, much like planets cirde surãin seres of concentric shells of increasing size. Each shell stood at a fixed (set) distance from the nucleus with the shell nearest the nucleus taking the m and a shell further away taking the n in the B-R equation. The integral values of m and n taken with the discrete wavelength led Bohr to propose the shells were "quantized," meaning electrons could only exist at the surface of the shells. When an electron moved from a high shell, n, to a low shell, m, light of a foxed wavelength was emitted Bohr reasoned the shells were special due to this quantized nature. An electron in a shell occupied what Bohr described as a "steady state," meaning the electron could circulate about the nucleus without loss or gain of energy. This steady state proposition, which conflicted with classical physics, could not be explained by then available data but was required for Bohr's proposed structure to be stable. Later work revealed the wave-particle duality of the electron which lead to acceptance of the Steady State Proposition. The energy of an electron in any shell, represented by n, can be calculated using an equation derived from combining the Balmer-Rydberg and Planck equations. The energy of an electron in the no shell is given by é¦¯.h RL where hcR,-2.18x10-*) where Ru, is the Rydberg's Constant for the hydrogen atom, h is Planck's Constant and c is the speed of light NOTE: The energy is given a nexative value to refect the stabillting, attractive force between the negatively charged electron and the positively charged nucleus. As the shell number n increases, the attractive force decreases leading to a rising shell energies (E, increases, values less negative). ACTIVITY Calculate the energles for an electron in the first 7 shells of the hydrogen atom using the above relationship, recording the values in the center column of the Hydrogen the right-hand column in the table, convert the shell with the exponent of 10 Improper sclentific notation is typically used to plot data covering several orders of magnitude (powers of ten). Shell Energy Table. For energies to improper scientific notation Hydrogen Shell Energy Table Shell Value, n Calculated Shell Energy.ã Express Shell Energy in improper Scientific Notation, x 10-1 Page 9 of 12

1.An inorganic base dissociates in water into ?a)one or more hydrogen ions and one or more anions b)one or more hydroxide ions and one or more reactions c)one or more hydrogen ions and one or more captions d)one or more hydroxide ions and one or more anions 2.An atom becomes a cation by? a)accepting electrons into its outermost electron shell b)giving up electrons from its outermost electron shell c)donating protons to another atom d)accepting proton from another atom 3.An atom of oxygen has 8 protons ,8electroenes and 8 neutrons.How would you expect the electrons to be arranged in this atom? a)all electrons are located in the nucleus of the atom b)all 8 electrons are located in the outermost electron shell c)all 8 electrons are located in the electron shell nearest the nucleus d)2 electrons are in the electron shell nearest the nucleus and 6 are in the second shell 4.Which solution is acidic? a) H2O b)H2O+ NA(+) +OH(-) c) H20+H(+) +Cl (-) d)Na(+) + HCO3 (-) 5.which of the following is true about the products of the chemical reaction?a) in the synthesis reaction , the products contain the fewer atoms than the reactants b) in the synthesis reaction , the products contain more atoms than the reactants c)in any chemical reaction the products may contain more or fewer atoms than the rectants because the reaction is a random event d)the products of chemical reactions always contain the same number of atoms as the reactants 6.Can you choose which thing is not like others ? a)lactose b)maltose c)sucrose d )fructose 7Which of the following is not organic compound? a)CO2 b)H2O c)CH2O d)NH3 8.Which of the following is a lipid ? a)C6H12O6 b)C22H44COOH c)C2H4NH2 d)CO2 9.Which of the following does not dissolve readily in a water? a)proteins b) amino Acids c) steroids d) Carbohydrates 10.Which of the following is organic asid? a)H2CO3 b)NaOH c)HCL d)KCL 11.Nitrogen is the element important to the composition of ? a)carbohydrate b)proteins and nucleis acids c)fats d)glycerol 12.Which of the following is protein ? a)sucrose b) cholesterol c)raffinose d)mannose 13.In the formation of a polymer , dehydration synthesis occurs between ? a) the amino groups of 2 different amino acids b)the acid groups of two different amino acids c)the amino group of one amino acid and the acid group of the other d)all of the above

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CHEM 001 Lecture Notes - Lecture 7: Dmitri Mendeleev, Neon Sign, Incandescent Light Bulb

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