CHEM 001A Lecture Notes - Lecture 9: Thermal Equilibrium, Thermodynamics, Calorie

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Change in oxidation state results from gain or loss of electrons. Review oxidation numbers: ch4(g) + 2 o2(g) co2(g) + 2 h2o(g, h2o = -2 (o) + 2 (h2, ch4 = -4 (c) + 4 (h4) Practice: balancing redox reactions: a nail made of fe(s) that is placed in a solution of a soluble pd2+ salt gradually disappears as the iron enters the solution as fe3+. (aq) fe3+(aq) + mn(aq: 5fe2+(aq) 5fe3+(aq) + 5e, mno4. (aq) + 8h+ + 5e- mn2+(aq) + 4h2o: 5fe2+ + mno4. +8h+ 5fe3+ + mn2+ + 4h2o. F is force. d is distance: or w = p v, p is pressure, v is change in volume, work done by the system = energy lost by the system, hence the negative sign. Units of energy (heat and/or work: calorie (cal) the amount of heat necessary to raise the temperature of 1 g of water by 1oc.

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