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11 Dec 2019

Hydrogen and carbon dioxide can be used to produce carbon monoxide according to the water-gas shift reaction given by: H2 + CO2 = CO + H2O.

If a reaction is set-up initially with n moles each of H2 and CO2 and none of either of the products, CO and H2O, and the variable x represents the fraction of H2 dissociated at equilibrium. Complete the following table in terms of n and x.

H2

CO2

CO

H2O

Total moles

Moles at reaction start

n

n

0

0

2n

Moles at equilibrium

N(1-x)

2n

At T=298 K, the equilibrium constant for this reaction is Kp(298)=10-5. The value of x at 298 K(to a precision of 0.00001)

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Deanna Hettinger
Deanna HettingerLv2
13 Dec 2019

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