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11 Dec 2019

If a water supply has a pH of 8.70, what percentage of the free chlorine is in the form of HOCl on a molar basis?

Hints: For HOCl, pKa = 7.54. (Remember to use units of moles/L with pK values.)

In drinking water, free chlorine is the sum of hypochlorous acid and hypochlorite ion, i.e., free chlorine = [HOCl] + [OCl−] (using units of moles/L). Cl2 is negligible under these conditions.

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Jamar Ferry
Jamar FerryLv2
13 Dec 2019

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