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11 Dec 2019
The reaction mechanism: C <-> A + A (fast), involves k1, k-1
A + B --> P (slow), involves k2
involves an intermediate: A
Deduce the rate law for the formation of P.
d[P]/dt = k2*(k1/k-1)^2 * [C]^3 * [B]
d[P]/dt = k2*sqrt(k1/k-1) * sqrt([C]) * [B]
d[P]/dt = k-1*sqrt(k1/k2) * sqrt([C]) * [B]^2
d[P]/dt = k2*k1/k-1 * [C] * [B]
The reaction mechanism: C <-> A + A (fast), involves k1, k-1
A + B --> P (slow), involves k2
involves an intermediate: A
Deduce the rate law for the formation of P.
d[P]/dt = k2*(k1/k-1)^2 * [C]^3 * [B] | ||
d[P]/dt = k2*sqrt(k1/k-1) * sqrt([C]) * [B] | ||
d[P]/dt = k-1*sqrt(k1/k2) * sqrt([C]) * [B]^2 | ||
d[P]/dt = k2*k1/k-1 * [C] * [B] |
Elin HesselLv2
13 Dec 2019