CHEM 312 Study Guide - Final Guide: Wavenumber, Polarizability, Bond Order

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Polarizability is the same trend as atomic radius. Relationship between bond length, strength, bond order, and wavenumber. As the bond order increases, the bond strength also increases, decreasing the bond length. As the bond strength increases, so does the wavenumber. Bond order, strength, length, wavenumber. The orbitals are different energies electronegative atom, lower energy orbital more. Ir active - some change in dipole during a vibration of the molecule. X, y, z and (x,y) counts as 1. Raman active - some change in polarizability during vibration of the molecule. Xy, xz, zy, x 2 -y 2 , x 2 , y 2 , z 2. Sigma bond - filled sigma from the co bond donates electrons to empty d orbital on m. Pi bond - filled d from the m donates electrons to empty pi* orbital on co. This decreases the bond strength of the co and decreases the wavenumber. Acids in general accept electrons and bases donate electrons.

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