CHM136H1 Chapter Notes - Chapter 5: Bond Length, Haloalkane, Diethyl Ether

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24 Jan 2017
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CHM136H1 Full Course Notes
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Midterm 2 - chapter 5 (power point notes) We have two types of isomers: constitutional: which are with different atom connectivity, stereoisomers: which are with different geometries but the atom connectivity is the same. E opposite side of double bond for groups of higher priority. Z z for zame side of double bond for groups of higher priority. Double bond is treated as a single bond of the same molecule. Achiral symmetric contain mirror image super imposable. Chiral asymmetrical do not contain a mirror image not symmetric if same compound but on different sides (cis / trans) non. Super imposable molecule can be chiral even if there are no. Chiral centers (4 different groups surrounding the carbon) *enantiomers= configuration must be opposite at all chiral centers (r to s) *diastereomers = configurations not opposite at all chiral centers an achiral molecule symmetrical, can have chiral centers this is a.

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