BIOL 4087 Chapter : Chapter 17 Nirogen Fixation And Amino Acid Metabolism

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15 Mar 2019
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Chapter 17: nitrogen fixation and amino acid metabolism. + + -keto acid + nadph a. a. Sources of -keto acids synthesis include the tca cycle, Nitrogen fixation is the conversion of n2 to nh3. However, nitrogen fixation by plant bacteria is most important. N2 is very stable so to break this, a lot of energy is needed which comes from atp. Atp actually binds to the oxidized fe (ferredoxin) and accepts an electron to become the reduced form of fe. Ferredoxin (with fe-s cluster) acts as an electron donor, and protons are required to add hydrogen to nitrogen, forming ammonia. Electrons carried by ferredoxin are provided by nadph. Atp hydrolysis is necessary for the delivery of the electron to the reduced mofe. To break down one mole of n2 to 2 mole of nh4+ 16 atp are required. Nitrogenase is an enzyme that fixes atmospheric nitrogen gas (dinitrogen, n2). It is the only known family of enzymes that accomplish this process.

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