CHM 2211 Chapter Notes - Chapter 24: Ketone, Aldehyde, Chloroform
~Carbonyl condensation -
°2molecule Sof aldehyde
or
with each other
Cneeds base )ketone
,pica
'
base
?0:
-OH ,Hz 00OH
zIt -7 11 I
^-"a
it 9td@
.-aaddition
Mechanism
-
Nucieopnile
Problem 24.1 :Draw A Idol product
aTONE
. ÷I
#ko¥'Qy¥"
="i
µ
ain
Est
tea
#Ew⇒⇐€¥¥
"
a. get got
-Retro syn -
• Heat +-OH -reconverts to starting
material
-OH ,Hz° G
:p :p "
-7
2"
a←
it
^
H a
problem 24.3
a'
ifI
H%f xz
b.
/I€0"°×z
-Dehydration -
Aftp.OL -7dehydration
:* ÷±o .ie .÷'s .ir
=
Dehydration )
Sometimes
not Isolated
AKA EICB mechanisms ;÷E÷I
.FI#otIl
C.
-7 µ\ t HZO
