CHEM 1620 Chapter Notes - Chapter 16: Arrhenius Equation, Reaction Rate Constant, Rate Equation
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Chemical reactions vary greatly in the speed at which they occur. Some are essentially instantaneous, while others may take years to reach equilibrium. The reaction rate for a given chemical reaction is the measure of the change in concentration of the reactants or the change in concentration of the products per unit time. The speed of a chemical reaction may be defined as the change in concentration of a substance divided by the time interval during which this change is observed: For a reaction of the form a+b c, the rate can be expressed in terms of the change in concentration of any of its components rate= [a]/ t rate= [b]/ t rate= [c]/ t. Consider now a reaction in which the coefficients are different: Example 1 - for the oxidation of ammonia. Rate=- [a]/ t=- [b]/3 t= [d]/2 t it was found that the rate of formation of n2 was 0. 27 mol l 1 s 1.