CHM102 Lecture Notes - Lecture 11: Photon, Ionic Radius, Metallic Bonding

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30 Jun 2018
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Periodic Variations of Properties of the Elements
- The periodic table reflects the law of chemical periodicity. The properties of the
elements that will vary periodically with their atomic numbers include:
- Melting and boiling points
- Degree of metallic character
- Oxidizing or reducing properties
- Atomic radius
- Ionization energy
- Electron affinity
- Ion size
- Charge of simple ions
- Electronegativity
Atomic Radius
- In cases when atoms of the same element are bonded to each other in a
molecule (e.g., Cl2 or O2), the covalent radius is half the experimentally
determined distance between the two atomic nuclei.
- In cases of metallic elements, the atomic radius, called the metallic radius, is half
the experimentally determined distance between the nuclei of adjacent atoms in
a crystal.
Trends in Ionization Energy
- The first ionization energy (IE1) is the minimum energy required to eject an
electron from an atom in its lowest energy state.
- The magnitude of the first ionization energy increases across each period and
decreases across each group.
Successive Ionization Energies
- If more than one electron can be removed, atoms will have a series of ionization
energies.
- Each successive ionization energy (i.e., second, third, etc…) is larger than the
previous one.
Ionic Radius
- An ionic radius is the estimate based on the distance between the cations and
anions in its crystalline compounds.
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Document Summary

The periodic table reflects the law of chemical periodicity. The properties of the elements that will vary periodically with their atomic numbers include: In cases when atoms of the same element are bonded to each other in a molecule (e. g. , cl2 or o2), the covalent radius is half the experimentally determined distance between the two atomic nuclei. In cases of metallic elements, the atomic radius, called the metallic radius, is half the experimentally determined distance between the nuclei of adjacent atoms in a crystal. The first ionization energy (ie1) is the minimum energy required to eject an electron from an atom in its lowest energy state. The magnitude of the first ionization energy increases across each period and decreases across each group. If more than one electron can be removed, atoms will have a series of ionization energies. Each successive ionization energy (i. e. , second, third, etc ) is larger than the previous one.

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