CHEM1201 Lecture 22: Week 11 lecture 1

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Liquids and solids:
Revision:
Liquids: evaporation
- Vaporisation:
o A few molecules at the surface have enough energy to escape the attractions
of their neighbours
o They enter the gaseous state
- Condensation:
o At the same time, some molecules in the gaseous state can re-enter the
liquid
Evaporation in a closed system:
- In a closed system, a dynamic equilibrium is established
-
Equilibrium vapour pressure:
- The boiling points of liquids: when the equilibrium vapour pressure ATM pressure
- In a closed system, the vapour pressure of a liquid comes to a constant value, called
the equilibrium vapour pressure
- The equilibrium vapour pressure is a measure of the tendency of molecules to
escape from the liquid phase and enter the vapour phase
- Equilibrium vapour pressure is temperature dependent
o temperature equilibrium vapour pressure of liquid
- volatile liquids (weak intermolecular forces) have high equilibrium vapour pressures
-
- ***he eplaiig, ake sue to sa eual ates***
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