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Class Notes (1,032,714)
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UniMelb (5,189)
CHEM (185)
CHEM10006 (45)

Class Notes for CHEM10006 at University of Melbourne

Chemistry for Biomedicine

CHEM10006 Lecture Notes - Lecture 33: Water Softening, Transition Metal, Hematite

Transition metals Complexes The acidity of the aqua complex depends on the charge of the metal ion. Equilibrium is further to the right for an Fe3+ complex than an Fe2+ complex Oxido and hydroxide anions bridge metal ions ...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 31: Covalent Bond, Lone Pair, Nernst Equation

Redox chemistry part 2 Calculating cell potential based on pH The Nernst equation allows us to calculate the potential at intermediate pHs standard reduction potentials depend on pH, and are based on unit concentration...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 32: Transition Metal, Ferrous, Bioavailability

Redox Chemistry Transition Metals When transition metal cations are formed, their 4s electrons are lost first. Many transition metal ions have unfilled d orbitals. For the first several transition metals in the fourth peri...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 30: Nernst Equation, Membrane Potential, Reaction Quotient

Redox chemistry part 1 Revision OiL RiG oxidation numbers oxidant causes oxidation and is reduced and vice versa know steps to balance half equations galvanic cells Daniell cell The Nernst equation Cell potential wh...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 34: Enterobactin, Linkage Isomerism, Catechol

CHEM1006 Revision Notes Redox chemistry part 1 Coordination compounds nomenclature 1. Cation is named before the anion. 2. Ligands are named before the metal ion. 3. Ido or ato (8) is added to the root name of the ligand i...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 26: Rate-Determining Step, Electrophilic Addition, Elimination Reaction

Elimination and electrophilic addition reactions Summary - An elimination reaction is where an atom or group of atoms is lost and a multiple bond is formed - Two mechanisms that can be distinguished by rate measurement - ...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 21: Hydrogen Bond, Addition Reaction, Hydrohalogenation

Nomenclature, reactivity of alkenes and carbocations Trisubstituted alkenes - Cis and trans nomenclature depend on which atom is being referred to. - If two diastereomers cant be classified by cis and trans (i.e. trisubst...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 28: Nucleobase, Anomer, Reducing Sugar

Carbohydrates Revision - The biggest difference between carbohydrate molecules is whether the groups are axial or equatorial - Nomenclature aldehyde or ketone Number of carbons (tri, tetra, penta, hexa etc) -ose suffix...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 27: Thionyl Chloride, Carbonyl Group, Nucleophilic Addition

Reactions of the carbonyl group The carbonyl group - Carbonyl group is polar, thus acts as an electrophile rather than a nucleophile like ...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 25: Walden Inversion, Sn2 Reaction, Stereocenter

SN1 vs SN2 reactions Overview Cat #1 finds Cat #2 on his comfy chair and wants to sit. He has two options. 1. In the SN2, the nucleophile (Cat #1) forms a bond to the ...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 23: Heterocyclic Compound, Benzene, Cytosine

Benzene and Aromaticity Resonance structures - Individual resonance forms are imaginary, not real the real form is an average, or resonance hybrid, of the different forms - Resonance forms differ only in the placement of...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 20: Racemic Mixture, Pi Bond, Trigonal Planar Molecular Geometry

Diastereomers Diastereomers - enantiomers with more than one chiral centre - stereo genic centres must be in opposite configuration to be isomers Enantiomers have identical physical and chemical properties they cannot b...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 29: Nucleophilic Substitution, The Boc Group, Carboxylic Acid

Amino acids to peptides and proteins Amino acids - amino acids contain a basic amino group and an acidic carboxyl group - O and S nucleophiles - some have neutral side chains, some are acid and amides - KNOW WHAT DISULFID...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 24: Organic Compound, Molecularity, Rate-Determining Step

Reaction mechanisms of alkenes etc Pheromones - can attract other insects and allow them to communicate with each other. The reaction coordinate - one step reactions (no intermediates) - two step reaction (one intermedia...

Chemistry
CHEM10006
Frances Separovic
CHEM10006 Lecture Notes - Lecture 22: Polymerization, Hyperconjugation, Carbocation

Carbocation stability and benzene Markovnikovs rule Due to carbocation stability; in unsymmetrical alkenes: - Hydrogen will end up on the side with more Hydrogens - X will end up on the side that has more substituents Wh...

Chemistry
CHEM10006
Frances Separovic
Inorganic Chemistry - Reference Guides

This Guide provides invaluable reference material to anyone who requires readily accessible information concerning the basic principles that underlie this complex science. The Guide carefully references the Periodic Table ...

Chemistry
CHEM 30100
All Professors
Permachart - Marketing Reference Guide: Iupac Nomenclature Of Inorganic Chemistry, Lithium Aluminium Hydride, Polyatomic Ion

p e r m a c h a rt s MT I n o r g a n i c C h e m i s t r y N o m e n c l a t u r e ...

Chemistry
CHEM 30100
All Professors
Permachart - Marketing Reference Guide: Locant, Parent Structure, Substituent

permacharts TM O r g a n icC h e m is t ryN o m e n c la t u r e Nam...

Chemistry
CHEM 22700
All Professors
Permachart - Marketing Reference Guide: Beta Particle, Beta Decay, Atomic Number

permacharts TM Periodic Table of the Elements ...

Chemistry
CHEM 11100
All Professors
Permachart - Marketing Reference Guide: Carnot Heat Engine, Carnot Cycle, Isentropic Process

permacha srtM PHYSICAL CHEMISTRY Basics Adiabatic process in which no heat is transferred into or out Internal energy The total kinetic and potent...

Chemistry
CHEM 11100
All Professors
Introductory Chemistry - Reference Guides

This Guide serves as a well organized and effective point of entry for anyone embarking upon the study of Chemistry. All fundamental terms are clearly organized in chart form, with illustrative graphics. More complex conce...

Chemistry
CHEM 11100
All Professors

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