CHEM 212 Lecture Notes - Nucleophile, Acetone, Weak Base
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23 Nov 2012
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5. a methyl, primary or secondary rx a strong nucleophile such as ro- or cn- a high concentration of nucleophile a solvent of relatively low polarity, such as acetone to discourage ionization moderate temperature to discourage elimination. Nucleophilic strength in protic solvents like h2o, h2o/ch3ch2oh, hcooh. Rs- > cn- > i- > ch3ch2o- >oh- > br- > aro- > cl- > ch3coo- > no3. Nucleophilic strength in aprotic solvents like acetone or dmf or dmso. > cl- > f- >>> oh-, sh-, ro->>r-, h-
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