CHEM 1R03 Lecture Notes - Lecture 35: Carboxylic Acid, Molar Mass, Methyl Group

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Chemistry Lecture 35
Aldehydes and Ketones
Both aldehydes and ketones contain C=O and a carbonyl group
In ketones, the carbonyl group is attached to two carbon atoms either in the middle
of a chain or ring
R1 and R2 can not equal hydrogens, however it could be a methyl group for
example
In aldehydes, the carbonyl group is attached to a carbon and hydrogen
However, it can also be attached to two hydrogens in the case of formaldehydes
The attachments must always be at the end of the chain
In this case, both R1 and R2 can equal hydrogen
To name aldehydes and ketones, first select the longest chain of the carbon atoms
containing the carbonyl group
Number the chain from the end closest to the carbonyl group —> number the chain
calling the carbonyl C position 1
Then determine the parent name from the number of carbon atoms in the chain and
replace the final -e with -one for ketones but -al for aldehydes
Remember to name the alkyl branches as usual
Carboxylic Acids
These acids have a carboxyl group: R1-COOH and are
always at the end of the chain
Contains a acid functional group (weak acid)
To name these, select the longest chain of carbon atoms
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