CHMA10H3 Lecture Notes - Lecture 9: Delta Wing, Exothermic Reaction, Jmol

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25 Apr 2018
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CHMA10H3 Full Course Notes
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CHMA10H3 Full Course Notes
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Lec 9 - w = -f x d (f = force vs d = distance) Delta u = q + w -> w = -p delta v -> hard to take away p unless under vacuum. > take away delta v by having constant vol so that delta v = 0. Heat measured w/ calorimeter qv/n = deltaru (j/mol) Constant vol/bomb calorimetry to determine heat of reaction but x work under that condition -> consider atmospheric pressure as a constant. Enthalpy (h): sum of internal energy of system added to pdt of pressure & vol; H: state func; heat evolved @ chem reaction @ constant pressure. Enthalpy change (delta h): heat evolved in a reaction @ constant pressure -> conditions are diff than bomb calorimetry (constant vol) -> x interested @ work done. Exothermic reaction = release heat = -ve delta h coffee-cup calorimetry:

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