CHM136H1 Lecture Notes - Lecture 2: Valence Bond Theory, Trigonal Planar Molecular Geometry, Trigonal Pyramidal Molecular Geometry

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CHM136H1 Full Course Notes
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CHM136H1 Full Course Notes
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A volume of space where an electron can be. If n = 2 2s + 2px + 2py + 2pz (all 2p_ are degenerate; have the same energy) If n = 3 2s + 3-3p + 5-3d. Electrostatic forces of attraction between oppositely charged ions. Non-directional bond: ionic solids form because oppositely charged ions are attracted to each other in all directions. Atoms cannot be too far or too close. Too far has not strong enough attraction. Covalent bond: two electrons shared between two nuclei. Lewis structures: a representation of covalently bonded molecules. Determining the shapes of molecules based on repulsion/attraction between electron groups surrounding atoms. Electron group = single, double, triple bond or lone pair. Linear = 180 , trigonal planar = 120 , tetrahedral ~ 109. 5 . Tp bent if 1 lone pair. T-h trigonal pyramidal if 1 lone pair. Single bonds = sigma bonds ( ) sp3 orbitals.

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