Chemistry 2374A Lecture Notes - Lecture 18: Inexact Differential, Exact Differential

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Most chemical processes occur at constant pressure (for example: a chemical reaction occurs in a beaker that is open to the atmosphere will have pext = constant = 101. 3 kpa. Pressure (p) = constant applications are more common, more convenient, and easier to implement in the lab than v = constant. Attempting to maintain v = constant can result in explosions if the container fails (during high pressure and the container is not strong enough) The (cid:498)p(cid:499) stand for that the pressure is constant in the chemical reaction work from (cid:498)additional(cid:499) can be removed. If there is no additional work done on the system that is non-compression based, the. Some of the energy supplied by heating will escape back into the surroundings as pv work. Answer: while having the pressure constant will have the du < dqp (the differential for heat is. Answer: having constant volume will have whatever energy (cid:498)invested(cid:499) or go into the system to be (cid:498)conserved(cid:499).

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