CHEM 111 Lecture Notes - Lecture 12: Standing Wave, Cucurbituril, Azimuthal Quantum Number

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Lab writeups due at 5pm (3 and 4) Some particle in a box systems we are studying. Cucurbituril cages molecular cages, just like a pumpkin - shaped like it and can cut the top or bottom to get at the inside. Physics definition - have the same energy must degenerate wavefunctions have the same shape? (a: no) orientation? (a: no) The schrodinger equation for h gives allowed electron energies than bohr"s model. Exactly the same as predicted by bohr (should not be surprising) Note than n doesn"t have anything to do with angular momentum. What makes the h atom different from a particle in a box? (potential energy term is different) Central electrostatic potential in h atom gives different solutions than ib n is not the only quantum number called the principal" quantum number. Other quantzation conditions give additional quantum numbers l: angulat momentum q. n. ,= 0,1 n-1 (n of these for each value of n) m:magnetic q. n.