Chemistry CHEM S-20ab Lecture Notes - Lecture 18: Ylide, Ketone, Amide

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30 Apr 2018

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!""#$%$ &'()$*+,$-.*%$$

B5")4&C9)!"1;,-.6$$

7)3@F"A>a>3E$=(#"3"A$HD9B$J?DC93)(A$

Reading6$7"5893$*:;*K$ K:$

PF"$!>bE$D"?5893$>A$?$D"B?D#?C()$'A"H'($A)3@F"A>A$9H$?(#"3"A;$$c>DA@,$?3$?(#)($F?(>4"$

>A$'A"4$@9$H9DB$?$>5-%>5-.&D=)2(&+"E$$LD9M>4"$?$5'DM"41?DD9I$B"5F?3>AB;$

PF"3$@F"$/F9A/F93>'B$)(>4"$>A$?44"4$@9$?3$?(4"F)4"$9D$#"@93"$@9$)>"(4$?$3"I$5?DC931$

5?DC93$+-D'("$C934`$$LD9M>4"$?$B"5F?3>AB;$

dd$PF"$!>bE$D"?5893$@"34A$@9$E>M"$cis$?(#"3"A$IF"3$@F"D"$>A$?$5F9>5";$dd$

Br PPh3

PPh3n&BuLi

phosphonium)ylide)

PPh3

H+

PPh3

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!""#$%$ &'()$*+,$-.*%$$

B5")4&C9)!"1;,-.)&.)F2./5"%&%)

Reading6$7"5893$*:;*K$ %.$

09I$I9'(4$)9'$5?DD)$9'@$@F"$H9((9I>3E$@D?3AH9DB?893Q$

Cl2C

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