Chemistry CHEM S-20ab Lecture Notes - Lecture 21: List Of Named Devils In Dungeons & Dragons, Teratology, Enol
30 Apr 2018
School
Department
Course
Professor
!""#$%$ &'()$**+$*,-.$$
Enols%&%Enolates:%%
/01234)($/3563'478$08$9':("36;<("8=>?@$
ReadingA$B":C34$**D-$ EF$
!;0G$H<(($;066"4$<I$)3'$G1"0G$acetone$H<G;$-$"J'<K0("4G$3I$0$K"1)$8G134L$208">$
M;"$1"8'(C4L$86":<"8+$:0(("7$04$enolate+$:04$2"$0$base)31$0$nucleophile+$047$<8$G;"1"I31"$
#43H4$08$04$ambident.nucleophileD$$B;3H$G;"$two)6137':G8$G;0G$:04$1"8'(G$I135$G;"$$
613G340C34$3I$G;<8$"43(0G"D$$N3$)3'$1":3L4<O"$G;"8"$6137':G8>$
B;3H$G;"$"43(0G"$G;0G$H<(($1"8'(G$I135$G;"$7"613G340C34$3I$G;"$538G$0:<7<:$613G34$
<4$"0:;$3I$G;"$I3((3H<4L$86":<"8A$
O
H
O
H
O
O
O
!""#$%$ &'()$**+$*,-.$$
Enols%&%Enolates:%%
6K08$3I$/01234)($/3563'478$
ReadingA$B":C34$**D-$ P,$
QR6(0<4$G;"$G1"478$<4$6K0$K0('"8$I31$G;"$I3((3H<4L$:01234)($:3563'478D$
Q0:;$3I$G;"8"$:3563'478$<8$G1"0G"7$H<G;$G;"$208"$sodium)ethoxideD$$!;0G$H<(($G;"$$
predominant$86":<"8$2"$0G$"J'<(<21<'5$<4$"0:;$:08">)
R
O
OR'
O
HH
RO
O
OR'
O
HH
CH2R'R
O
CH2R'RO
O
N C CH2R
R
O
OR'
O
HH
RO
O
OR'
O
HH
CH2R'R
O
CH2R'RO
O
N C CH2R
EtO)
EtO)
EtO)
EtO)
EtO)
6K0$ /34S'L0G"$208"$
--$
$
$
-T$
$
$
$
*,$
$
$
*%$
$
T-$
