CHM 145 Lecture Notes - Lecture 2: Benzene, Partial Pressure, Formula Unit

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Dynamic equilibrium: rate of dissolution = rate of recrystallization. For most solids, solubility increases as temperature increases! Solubility of gases in a liquid solvent: henry"s law states that the solubility of a sparingly soluble, chemically unreactive gas in a liquid is proportional to the partial pressure of the gas above the solution. Sgas = khpgas where sgas = solubility of the gas in solution kh = henry"s law constant for the gas in a specified solvent at specific temperature. Pgas = partial pressure of gas above solution. He (kh = (cid:868). 7 (cid:937) (cid:866)(cid:865) (cid:869)(cid:858) (cid:914)(cid:933) (cid:933)(cid:921)(cid:918) (cid:932)(cid:914)(cid:926)(cid:918) (cid:933)(cid:918)(cid:926)(cid:929)(cid:918)(cid:931)(cid:914)(cid:933)(cid:934)(cid:931)(cid:918). Affect physical properties: solubility stronger interactions higher solubility (solute-solvent, freezing / melting points stronger interactions higher melting point, vapor pressures stronger interactions lower vapor pressure, boiling points stronger interactions higher boiling point. Concentration ratios: %, ppm, & ppb: percent (%): mass % =

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