CHM 145 Lecture 10: CHM 145 2/7/17

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In an experiment, 1. 0 mol of n2o4 is placed in a 10. 0 l vessel and is allowed to react as described below. N2o4 (g) <===> 2no2 (g) kc = 4. 0 x 10-7 calculate the concentration of each species at equilibrium. = [no2]2 = [2x]2 = 4. 0 x 10-7. X2 = (4. 0 x 10-7) (. 10) = 1. 0 x 10-4. [no2]2 = 2 x 1. 0 x 10-4 = 2. 0 x 10-4 m. 0. 100-. 00010 = . 10m: the following reaction has an equilibrium constant, kc, equal to 3. 59 at 900oc. Ch4(g) + 2h2s (g) cs2 (g) + 4h2(g) For each of the following compositions, decide whether the reaction mixture is at equilibrium. If it is not, decide which direction the reaction will shift: [ch4]=1. 26m, [h2s]=1. 32m, [cs2]=1. 43m, [h2]=1. 12 m. [ch4][h2s]2 [1. 26][1. 32]2 2. 195: [ch4]=1. 25m, [h2s]=1. 52m, [cs2]=1. 15m, [h2]=1. 73 m. [cs2][h2]4 = [1. 15][1. 73]4 = 3. 57=3. 59 within experimental error. [ch4][h2s]2 [1. 25][1. 52]2: [ch4]=1. 20m, [h2s]=1. 31m, [cs2]=1. 15m, [h2]=1. 85 m.

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