CHM 11500 Lecture Notes - Lecture 23: Osmotic Pressure, Melting Point, Colligative Properties

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Chm 115 - lecture 23 - properties of solutions. Concentration is the amount of solute that is dissolved in a unit amount of solvent. Concentration = (amount of solute) / (amount of solvent or solution) Molarity (m) is the number of moles of solute dissolved in one liter of solution. Molarity = (moles of solute / liters of solution) Molality (m) is the number of moles of solute dissolved in one kilogram of solvent. Molality = (moles of solute / kilograms of solvent) Mole fraction (x) is the number of moles of solute dissolved in one mole of solvent plus solutes. Mole fraction = (moles of solute)/(moles of solvent + moles of solute) Different units of concentration are useful for different types of analysis/calculations. Colligative properties are properties of solutions that are influenced by the amount of solute in the solution, and not affected by the type of solute.

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DETERMINATION oF MOLAR EXPERIMENT 23 MASS FROM FREEZING POINT DEPRESSION EQUIPMENT AND CHEMICALS: Equipment 600 mL beaker Chemicals Cyclohexane (C Stir plate 100 ml. graduated cylinder Clamp Nonvolatile Unknowns Freezing point apparatus Spin vane 0.1 C Thermometer INTRODUCTION: When a solute is introduced into a pure solvent the newly formed solution will have certain physical properties that are from the solvent. As a of the presence of the the pressure of the solution will be lower than that of the pure solvent. As the vapor pressure is lowered there is a resulting increase in the amount of energy required to reach the boiling point of the solution. Conversely, the solution must cool to a lower temperature before a state change from liquid to solid occurs. These changes in physical properties vapor pressure lowering, boiling point elevation and freezing point depression are collectively referred to as colligative properties. These colligative properties, which also include osmotic pressure, do not depend on the nature of the nonvolatile solute in the solution but rather on the concentration of solute present. Because the properties are independent of the nature of the solute, they may be used to determine other properties of the solute such as molecular weight. The effect of a nonvolatile, nonelectrolyte solute on a pure solvent will be examined by finding the freezing point depression of a cyclohexane unknown so solution. The freezing point of a pure sample of cyclohexane will be determined. Introducing a nonelectrolyte solute should in solution formed to freeze at a lower temperature. This temperature will then be experimentally determined As stated the The molality of the solution dependent on the quantity of solute particles present in solution. (moles solute particles per kilogram of solvent) is directly proportional to the change in temperature between the freezing point of the pure solvent and that of the ATfss Kim The molal freezing point depression constant, K for cyclohexane is equal to 20.00 cfmolal By experimentally determining the freezing point depression of a ohexanel unknown solution, the molal concentration is easily calculated. In turn the molar mass of the unknown olute can be calculated as well Chemistry 132 EXPERIMENT23

Experiment 10 Colligative Properties Introduction A pinch of wa make boiling water hotter. A handful will clear the snow from your steps. Every day we the physical properties of materials around us, but often don't know why we use these particular s or what chemistry is involved. Modifying the temperature of phase changes, by adding a second chemical to the pure solvent are examples of manipulating the Colligative Properties of a solution. this lab, we will study how varying the concentration and type of a salt affects the point of a solution. Colligative properties are properties of a solution containing 2 or more components. Typically, the primary is the solvent and the other called the such as color or hardness, properties depend on the number of particles of astute in the not the identity of the In many cases, the rokute will determine the number of solute particles (degree of ionization, solubility, etc,) in the solvent, but a colligative property does not depend upon the nature of the particles. Two colligative properties commonly encountered are boiling point elevation and freezing point depression (the temperature of of a is lower than of pure solvent). We will be studying boiling point elevation in this Most of the previous work that you have done with solutions has involved units of molarity, M, or moles of solute per liter of solution. Boiling point elevation calculations (as well as those for freezing point depression) or moles of solute per kilogram of solvent. boili change of temperature. When the temperature of a solution changes, the volume of the solution also changes. Since molarity depends on a change in wil the solution's molarity. Molality depends on the mass of the solvent. and thus is independent of temperature. n't Hoff Factor salt into and the of moles inorganic salts in an aque the based on the addition of the number dissociates, the total number of particles in the solution will be of cations and anions produced from the dissociation. Thus; Nacion Na Choaa (2moles of particles) Cacbrs Ca +2ch (3moles of particles) The quantity of particles produced per mole of solute is called the van'tHoff factor and is given the symbol, i, If 1 mole of sodium chloride were completely dissociated, iwould be 2. This theory works very well for dilute solutions and non-electrolytes (i 1, no dissociation at all since nonelectrolytes not ionize), For does not always apply to more concentrated solutions. Thus, when there are a large number of particles in a solution, they have a tendency to recombine as the salt and you don't get 100% dissociation. example, at a NaCl concentration of 0.1M, iwill be 1.81 (90% dissociation) rather than 2 (100%). Boiling Point Elevation solute causes the solution to boil at a higher When a solution is heated, the presence of a non-volatile point of the pure liquid and the temperature than the pure The difference between the boiling boiling point of the solution is: 169

7. Complete the following table:

Element Moles Mass Num

7. Complete the following table:

Element Moles Mass Number of molecules

13. It is the component that is in a solution, in smaller quantity.

a. Solution

b. Solvent

c. Solvent

d. Soluto

14. It is the component that is in a solution in greater quantity.

a. Solution

b. Solvent

c. Solvent

d. The answers b and c are correct.

15. The quantitative expression of the dissolved amount of solute in a quantity determined solvent is known as:

a. Solution

b. Volume

c. Concentration

d. Stoichiometry

16.Express the moles of solute among the liters of solution

a. Molality

b. Molarity

c. % weight by volume

d. % weight by weight

17.Express the moles of solute between kg of solvent

a. Molarity

b. ppm

c. ppt

d. Molality

18. What is the molarity of a solution prepared by dissolving 7.50 g of nitrate of magnesium, Mg (NO3) 2 in enough water to prepare 25.0 mL of solution?

a. 10.3 M

b. 5.6 M

c. 6.5 M

d. 2.03 M

19. How many grams of sodium chloride, NaCl are needed to prepare 125 mL of 0.037 M NaCl solution

a. 1.021 M

b. 0.268 M

c. 0.201 M

d. 0.500 M

20. Calculate the molality of a solution containing 12.5 g of ethylene glycol (C2H6O2) dissolved in 135 g of water.

21. A solution of ethylene glycol contains 21.2 g of ethylene glycol (C2H6O2) in 85.4 mL of water. Calculate the freezing point and the boiling point of the solution. (Assume the water density is 1.00 g / mL)

22. At what volume should you dilute 75 mL of a 10.0 M solution of H2SO4 to obtain a 1.75 M solution of H2SO4.

CHM 11500 Lecture Notes - Lecture 23: Osmotic Pressure, Melting Point, Colligative Properties

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