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CHM 11600 Lecture Notes - Lecture 7: Enzyme, United Nations Convention Against Torture, Activation Energy

Chm 11600 - general chemistry - lecture 7_catalysts. T-butyl bromide, c(ch3)3br, will react with methanol (ch3oh) at high temperature to make c(ch3)3 och3 and hbr. Reaction is a + b products. Step 1: a + b products. Catalyzed is two steps, including the catalyst. Step 1: a + cat c (slow) Step 2: b + c products + cat. Catalysts increase the rate of a reaction, but are not used (i. e. , not reactants). They do this by providing a different mechanism for the reaction to proceed. Catalysts increase the rate of both forward and reverse reactions, so they do not affect yield of a reaction, only rate. Higher k with catalyst = faster reaction. Second step is faster; first catalyzed step is rate determining. Reverse reaction is also faster with catalyst. The iodide ion catalyzes the decomposition of h2o2. Step 1: h2o2 + i oi- +h2o. Step 2: h2o2 + oi- h2o + o2(g) + i .

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CHM 11600 Lecture Notes - Lecture 7: Enzyme, United Nations Convention Against Torture, Activation Energy

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