CHM 2211 Lecture Notes - Lecture 3: Hydrogenation, Electrophilic Addition, Sigma Bond

15 views2 pages
School
Department
Course

Document Summary

Compounds can have more than one double bond. If they are separated by only one single bond, they are conjugated and their orbitals interact: electrons can move because there are p orbitals available in all four carbons, electrons are delocalized, electrons can move around the molecule. If they are separated by two single bonds, they are isolated: electro(cid:374)s ca(cid:374)"t (cid:373)ove arou(cid:374)d the (cid:373)olecule, not all carbons have p orbitals available, hence, electrons are localized. There can also be conjugation on carbocations: there are three p orbitals continuous and electrons can move about those 3 carbons with available p orbitals, stabilized by resonance, real structure is the hybrid of both resonant structures. + to 3o: allyl carbocations are as stable as 2o carbocations. Features of conjugated dienes: the single bond of the diene is shorter than normal sigma bonds, diene sigma bond 148 pm.

Get access

Grade+20% off
$8 USD/m$10 USD/m
Billed $96 USD annually
Grade+
Homework Help
Study Guides
Textbook Solutions
Class Notes
Textbook Notes
Booster Class
40 Verified Answers
Class+
$8 USD/m
Billed $96 USD annually
Class+
Homework Help
Study Guides
Textbook Solutions
Class Notes
Textbook Notes
Booster Class
30 Verified Answers

Related Documents

Related Questions