BENG 130 Lecture 4: Lecture 04

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29 Oct 2016

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(cid:1856)(cid:1847)=(cid:4672)(cid:3022)(cid:3021)(cid:4673)(cid:3023)(cid:1856)(cid:1846)+(cid:4672)(cid:3022)(cid:3023)(cid:4673)(cid:3021)(cid:1856)(cid:1848: we can represent energy as (cid:1847)(cid:4666)(cid:1848),(cid:1846)(cid:4667) (depends on volume and temperature, also, we know (cid:1856)(cid:1847)=(cid:1856)(cid:1843) (cid:1842)(cid:3032)(cid:3051)(cid:1856)(cid:1848) (because of the 1st law of thermodynamics, thus, (cid:4672)(cid:3022)(cid:3021)(cid:4673)(cid:3023)(cid:1856)(cid:1846)+(cid:4672)(cid:3022)(cid:3023)(cid:4673)(cid:3021)(cid:1856)(cid:1848)=(cid:1856)(cid:1843) (cid:1842)(cid:3032)(cid:3051)(cid:1856)(cid:1848) (cid:1856)(cid:1846)=(cid:1855)(cid:3023)(cid:4666)(cid:1846)(cid:2870) (cid:1846)(cid:2869)(cid:4667) Thus, (cid:1847)= (cid:1855)(cid:3023)(cid:3021)(cid:3118)(cid:3021)(cid:3117: (cid:4672)(cid:3022)(cid:3023)(cid:4673)(cid:3021)=(cid:1846)(cid:4672)(cid:3017)(cid:3021)(cid:4673)(cid:3023) (cid:1842)=(cid:1846)[(cid:4672) (cid:4673)(cid:3021) ](cid:3023) (cid:1842)=(cid:3019)(cid:3021)(cid:3023) (cid:1842)=(cid:1842) (cid:1842)=(cid:882, the stuff we did for u, we can do the same for h, where (cid:4666)(cid:1842),(cid:1846)(cid:4667), and we can get. Thus, internal energy of an ideal gas only depends on temperature: look at example problem 3. 5 in the book. Heat engines: main question: can i take a substance, take all the energy change, and use it all for work? (and not heat?) While we can convert all work into heat, we cannot convert all heat into work: consider an isolated system with an ideal gas. We want to do isothermal expansion, adiabatic expansion, isothermal compression, and then adiabatic compression. (cid:3018)(cid:3276)(cid:3277)(cid:3021)+(cid:3018)(cid:3278)(cid:3279)(cid:3021)=(cid:882) and t is constant: consider reversible isothermal expansion of an ideal gas.

Related Questions

As entropy increases there will be more useful energy to doâworkâ. True or false?

False. As entropy increases, there will generally be less usefulenergy to do work. We can think of entropy as usually being presentin the form of heat energy. Imagine a car motor, which attempts toturn chemical potential energy into kinetic energy (movement). Lessefficient motors will get hotter for the same amount of fuelconsumed. When you drive a car you hope that most of the fuelenergy is converted into kinetic energy and not lost as heat(entropy). The hotter the car (and thus the more entropy) the lessefficient the ability to do âworkâ (the moving of the vehicle).

True. As entropy increases, there will generally be more usefulenergy to do work. We can think of entropy as usually being presentin the form of heat energy. In most biological and mechanicalsystems it is heat energy which is captured to do useful 'work'.Heat energy, the random movement of molecules, and increases inentropy are central to doing useful work.

Biological systems sometimes appear on the surface to break theSecond Law of Thermodynamics â by seemingly increasing the order inthe overall system. They donât. Why?

a. Earth (and living things on it) are not a closed system. Thesun's constant input of energy in the form of photons is harnessedby living things to create internal order within themselves. Butwithout such a constant input of energy, most biological systems onearth would break down.

b. The Second Law tells us that no natural process can occurunless it is also associated with an increase in the entropy of theuniverse. A living organism (such as an animal or plant) brings inmatter and energy from its environment and uses this to creategreater order within its body: the processes of life. But it isimportant to keep in mind that all animals and plants are also partof a larger system of the environment around them. While creating asmall âpocketâ of order, the processes of life (metabolism,movement, etc..) releases heat into the environment â thusincreasing the entropy of the universe and following the2^nd law.

c. Living things, by harnessing energy to create order (withinand around themselves) actually create a paradox in questionssurrounding the first and second laws of thermodynamics andseemingly violate many previously held assumptions.

d. Both a and b above are correct.

When plants capture energy in the photons of sunlight andconvert that energy into the chemical bonds of organic molecules,are they creating new energy?

No, the energy is being transferred from one form into another.But no new energy is being created.

No, the overall total energy is decreasing over time.

Yes, by capturing photons, the plants are creating newenergy.

Yes, by capturing photons, the plants are creating new energy -of a different wavelength.

ceruleanhamster867

Question1.1. Accidental alterationsduring DNA replication that give rise to variations in organismsare __________. (Points : 1)

adaptive traits
mutations
symbioses
random distributions

Question2.2. The largest reservoir ofcarbon in the carbon cycle is comprised of _________. (Points :1)

freshwater systems andoceans
plants and animals
sedimentary rock andfossil fuels
atmosphere

Question3.3. The principle of utility________. (Points : 1)

holds that any naturalresource should be available for use in manufacturing
holds that something isright when it produces the greatest benefit for the greatest numberof people
is not an ethicalstandard
cannot be used toestimate the value of natural resources

Question4.4. The two processes thatdetermine current biodiversity on a global scale are __________.(Points : 1)

allopatric speciation andimmigration
mutation and habitatselection
mutation and globalclimate change
extinction andspeciation

Question5.5. The conservation ethicholds that we should ________. (Points : 1)

exploit natural resourcesfor economic gain regardless of sustainability
be prudent and efficientin the use of natural resources
consider the environmentthe ultimate servant of mankind
maintain the environmentin a pristine, unaltered state

Question6.6. The preservation ethicholds that we should ________. (Points : 1)

be responsible for wisemanagement while using natural resources
protect areas againstdevelopment while allowing public access
harvest naturalresources
maintain the naturalenvironment in a pristine, unaltered state

Question7.7. Trophic levels and foodchains diagram __________. (Points : 1)

logistic curves
energy flow in anecosystem
population density
natural resourcefluctuations

Question8.8. A hypothesis is ________.(Points : 1)

a prediction
an educated guess thatexplains a phenomenon or answers a question
an instrument that isused to examine environmental conditions
the design of anexperiment that can be used for the process of science

Question9.9. A biocentric view of theworld emphasizes ________. (Points : 1)

the role of corporationsin environmental law
the importance ofconsidering environmental impacts on all living things
the importance ofeconomics in environmental decisions
the dual-natured view ofhumans and animals as environmental controls

Question10.10. Malthus was responsiblefor ________. (Points : 1)

the book The PopulationBomb that described the disastrous effects of human populationgrowth
the idea that theincrease in human population would lead to famine and war
the concept that humanpopulation growth would lead to greater industry and prosperitythrough education
instituting fertilizeruse for agriculture

Question11.11. Ecology is ________.(Points : 1)

the study of how to solveenvironmental problems
the study of organismsand their interactions with each other and the environment
a subfield ofenvironmentalism
the study of the E. colifamily of bacteria

Question12.12. The scientific processis based on ________. (Points : 1)

observations thatresearchers keep in a scientific journal
testing hypotheses builton observation, and revising them based on results
intuitive understandingof natural laws and processes
the ancient writings ofHeraclitus

Question13.13. Which of the followingis an abiotic factor? (Points : 1)

Amphibians
Wood
Mammals
Water

Question14.14. In environmentalscience, "carrying capacity" means the ___________. (Points :1)

maximum population sizethat a given environment can sustain
average number of viableoffspring produced within a population
potential number ofspecies in a given area
limitation on the numberof species in an ecosystem

Question15.15. The Cuyahoga River madepeople aware of environmental problems because __________. (Points: 1)

people in manycommunities became sick when using water from the river
the drinking water inelementary schools near the river became contaminated
the river caught onfire
the river stoppedsupporting any plant or animal life

Question16.16. The conversion processwhere nitrogen gas combines with hydrogen to form ammonium ions,which is accomplished through the intense energy of lightening orwhen air in the top layer of soil comes into contact with certainbacteria, is known as ________. (Points : 1)

the carbon cycle
nitrogen fixation
ionic conversation
bacterial ionization

Question17.17. The fresh water wedepend on for survival accounts for approximately __________ of allwater on Earth. (Points : 1)

two-thirds
one-third
10%
3%

Question18.18. A paradigm is ________.(Points : 1)

a group of severalhypotheses that can be tested together
a dominant view inscience
the same as ahypothesis
synonymous with thescientific method

Question19.19. The degree of disorderin a substance, system, or process is called ________. (Points :1)

chaos
entropy
energy
electricity

Question20.20. A population is definedas ___________. (Points : 1)

a group of individuals ofmultiple, interacting species that live in a particular area
a group of similarspecies that inhabit various ecosystems
a group of individuals ofa single species inhabiting a particular area
(crude birth rate +immigration rate) - (crude death rate - emigration rate)

periwinklecoyote319

A catabolic pathway would predictably result in the
A) reduction of a sugar.
B) synthesis of a macromolecule.
C) breakdown of a macromolecule.
D) breakdown of an atom.
2.
The drug Ritonavir is used to treat people with HIV/AIDS. It worksby binding to the active site of HIV-1 protease, an enzyme used bythe AIDS virus to create new proteins for production of newviruses.Once bound, the HIV-1 protease cannot produce proteins.Ritonavir can be classified as a(n)
A) competitive inhibitor.
B) allosteric inhibitor.
C) activator.
D) non-competitive inhibitor.
3.
During cellular respiration, __________ is the final electronacceptor that allows the regeneration of the cellâs supply of NAD+.In fermentation, ____________ is the final electron acceptor forNAD+ regeneration.
A) pyruvate / lactic acid
B) pyruvate / oxygen
C) ethanol / CO2
D) oxygen / pyruvate
4.
Which of the following clues would tell you if a cell isprokaryotic or eukaryotic?
A) whether or not the cell carries out cellular metabolism
B) the presence or absence of ribosomes
C) whether or not the cell is partitioned by internalmembranes
D) whether or not the cell contains DNA
5.
Phosphofructokinase (PFK) is an allosteric enzyme that regulatesglycolysis. When cellular concentrations of ATP and citrate become__________, this enzymeâs activity decreases. When cellularconcentrations of AMP become ________, the enzyme isactivated.
A) high / high
B) high / low
C) low / high
D) low / low
6.
______________ is an enzyme that can utilize the free energy in thehydrogen gradient (voltage) produced between the inner and outermembrane of the mitochondrion. The enzyme uses this energy toproduce ________.
A) ATP synthase/ ATP
B) PFK/ ATP
C) PFK/ glucose
D) ATP synthase/ ADP
7.
ATP is able to do cellular work because it
A) has a high energy phosphate bond that can be hydrolyzed torelease energy.
B) converts light energy into chemical bond energy.
C) contains the sugar ribose, which can provide additional energyfor a cell.
D) its hydrolysis is endergonic.
8.
A solution of starch at room temperature does not readily decomposeto form a solution of simple sugars because
A) the starch solution has less free energy than the sugarsolution.
B) the activation energy barrier for this reaction cannot besurmounted.
C) the hydrolysis of starch to sugar is endergonic.
D) starch hydrolysis is nonspontaneous.
9.
A person exposed to toxins would have more activity in their___________compared to an unexposed person.
A) lysosomes
B) Golgi bodies
C) rough endoplasmic reticulum
D) smooth endoplasmic reticulum
10.
Which of the following statements about fermentation is true?
A) The function of fermentation is to regenerate the fermentingcells' supply of NAD+.
B) Fermentation allows a fermenting cell to gain more energy perglucose molecule than a non-fermenting cell.
C) Fermentation produces either lactic acid or ethanol that thefermenting cell can use as an energy source.
D) Fermentation is a universal process that occurs in all cells andall organisms.
11.
A glucose molecule is completely broken down to carbon dioxide andwater in glycolysis and the citric acid (Krebs) cycle, but togetherthese two processes yield only a few molecules of ATP. Whathappened to most of the energy that the cell obtains from theoxidation of glucose?
A) It was lost as heat.
B) It is stored in the carbon dioxide and water molecules releasedby these processes.
C) It is stored in the ATP that was formed by glycolysis and thecitric acid cycle.
D) It is stored in NADH and FADH2
12.
The First Law of Thermodynamics states that
A) entropy tends to increase in a system.
B) entropy tends to decrease in a system.
C) energy cannot be created nor destroyed.
D) the quality of energy in the universe is decreasing.
13.
The endosymbiotic theory states that _______________ evolved as aresult of a symbiotic relationship between different types ofbacteria. _____________ is thought to be the selective factor thatmade this symbiosis advantageous.
A) mitochondria / A change in the Earthâs atmosphere from anaerobicto aerobic
B) endoplasmic reticulum / A decrease in the amount of foodavailable in the environment
C) chloroplasts / A change in the Earthâs atmosphere from aerobicto anaerobic
D) lysosomes / A decrease in the amount of food available in theenvironment
14.
A mutation in a fruit fly affects one of the proteins that pumphydrogen ions across the inner mitochondrial membrane; thismutation makes that particular protein function less efficiently.When comparing aerobic cellular respiration in this fly with awild-type fly, you would predict that the mutant fly would
A) produce less ATP than a wild-type fly.
B) show no difference in ATP production when compared to awild-type fly.
C) produce more ATP than a wild-type fly.
D) not be able to produce any ATP via aerobic cellularrespiration.
15.
Proteins that are destined to be exported from the cell have unique_________________ that are recognized by signal recognitionparticles and thus moved to the _________________ duringtranslation.
A) phosphofructokinases / nucleus
B) codons / rough endoplasmic reticulum
C) signal recognition sequences / rough endoplasmic reticulum
D) signal recognition sequences / free ribosomes
16.
During the Krebs cycle
A) NADH is oxidized.
B) ATP is produced.
C) pyruvate is produced.
D) Acetly CoA gains a carbon to form pyruvate.
17.
Why does the oxidation of organic compounds by molecular oxygen toproduce CO2 and water release free energy?
A) Electrons are being moved from atoms that have a lower affinityfor electrons (such as C) to atoms with a higher affinity forelectrons (such as O).
B) The electrons have a higher potential energy when associatedwith water and CO2 than they do in organic compounds.
C) The covalent bond in O2 is unstable and easily broken byelectrons from organic molecules.
D) The covalent bonds in organic molecules and molecular oxygenhave more kinetic energy than the covalent bonds in water andcarbon dioxide.
18.
In a chemical reaction, if ?G is negative, it means that thereaction is
A) exergonic, and work needs to be done for the reaction toproceed.
B) exergonic, and work can be done with energy released from thereaction.
C) endergonic, and work needs to be done in order for the reactionto proceed.
D) endergonic, and work can be done with energy released from thereaction.
19.
The energy for an endergonic reaction comes from a(n) ___________reaction.
A) ADP + P --> ATP
B) endergonic.
C) exergonic.
D) anabolic
20.
Glycolysis
A) involves catabolic reactions and ATP is produced.
B) involves anabolic reactions and ATP is produced.
C) involves catabolic reactions and creates energy.
D) involves anabolic reactions and creates energy.

BENG 130 Lecture 4: Lecture 04

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