BIOL 2003 Lecture Notes - Lecture 5: Chemical Energy, Atp Hydrolysis, Endergonic Reaction

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11 Oct 2018
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The fate of a chemical reaction is determined by its direction and rate. Energy, the ability to promote change or do work. First: energy cannot be created or destroyed, but it can be converted from one form to another. (energy is conserved) Second law of thermodynamics states that energy interconversions increase entropy. Amount of available energy that can be used to promote change or do work. Change in free energy (g) determines direction of chemical reactions. Total energy (enthalpy h) =usable energy (free energy g)+ unusable energy (ts) H = enthalpy or total energy or chemical potential energy. G = free energy or amount of energy for work. T = absolute temperature in kelvin (k) G = h - t s. Exergonic (release energy) (entropy of product higher) G < 0 or negative free energy change. Atp + h2o adp + pi. Coupled reaction: glucose + atp glucose-phosphate + adp.

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