Lecture 592014.pdf

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CHEM 2332H
Christopher J.Douglas

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Lecture 592014Friday May 9 2014907 AMTodayPumiliotoxin CRetrosynthesissynthesis planFinal Exam Th 515 130330pm Smith 231 this roomNote we have many stereocenters in the target moleculeReduce w PdC H2convex faceMe is in equatorial this is favorableconcave faceFor hydrogenation concave side is more favorable bc needs to be flat on metals surface and it will stay put in placeand can control the nPr stereocenter Ochem Page 1
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