BIOL 201 Lecture Notes - Lecture 11: Atp Synthase, Peptide, Porphyrin

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Redox reactions: each electron transfer is a redox reaction. One carrier is oxidized, and the other is reduced. Succinate + fad + 2e + 2h -> fumarate + fadh2 + 2e + 2h. The next reaction is fadh2 + 2 fe (+3) (nhi) -> fad + 2fe+2 (nhi) + 2h. Nadh - > nad+, with the electrons going to the first carrier. The electron donor, is the reducing agent, that causes a reduction. Standard redox potential e0", a voltage value ranks reducing power of electron donor/acceptor pairs. The more negative the e0", the more the reducing power. Direction of electron transfer is from the more negative to the more positive. The first reaction of the electron transfer chain is the transfer of nadh electron to coenzyme q, which is then to complex iii, to cytochrome c, finally to complex iv. In the first reaction, electrons flow from carriers with more negative e0" to more positive ones.

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