CHM242H5 Quiz: quiz 9.pdf
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Please find the 75% equivalence point, 25% equivalence point, Difference in equivalence points, and half equivalence point(pKa1), and molecular weight range? Then based on the results, determine the unknown acid (possibilities: acetic acid, oxalic acid, benzoic acid, maleic acid, malic acid, and KHP).
standardized NaOH(M) is 0.0840±0.0005 and Used unknown acid was 0.2005g. I did titration curve graph, and found the end point as 44.40.
Below is a data of pH vs. NaOH titration:
V(NaOH), mL | pH |
0 | 1.69 |
0.5 | 1.67 |
1 | 1.68 |
1.5 | 1.68 |
2 | 1.69 |
2.5 | 1.7 |
3 | 1.71 |
3.5 | 1.73 |
4 | 1.74 |
4.5 | 1.75 |
5 | 1.76 |
5.5 | 1.77 |
6 | 1.78 |
6.5 | 1.79 |
7 | 1.8 |
7.5 | 1.81 |
8 | 1.82 |
8.5 | 1.84 |
9 | 1.85 |
9.5 | 1.86 |
9.5 | 1.87 |
10 | 1.88 |
10.1 | 1.89 |
10.2 | 1.89 |
10.6 | 1.92 |
11 | 1.93 |
11.2 | 1.94 |
11.5 | 1.95 |
12 | 1.96 |
12.1 | 1.98 |
12.3 | 1.99 |
12.5 | 1.99 |
12.7 | 2 |
12.9 | 2 |
13.1 | 2.01 |
13.3 | 2.01 |
13.5 | 2.02 |
13.7 | 2.03 |
13.9 | 2.04 |
14.1 | 2.05 |
14.3 | 2.06 |
14.5 | 2.07 |
14.7 | 2.08 |
14.9 | 2.09 |
15 | 2.13 |
15.5 | 2.14 |
16 | 2.16 |
16.5 | 2.2 |
17 | 2.23 |
17.5 | 2.26 |
18 | 2.3 |
18.5 | 2.34 |
19 | 2.39 |
19.5 | 2.43 |
20 | 2.48 |
20.5 | 2.54 |
20.7 | 2.6 |
20.9 | 2.63 |
21.1 | 2.65 |
21.2 | 2.66 |
21.4 | 2.69 |
21.6 | 2.72 |
21.8 | 2.74 |
22 | 2.77 |
22.2 | 2.8 |
22.5 | 2.83 |
23 | 2.89 |
23.5 | 2.94 |
24 | 3.01 |
24.5 | 3.08 |
25 | 3.13 |
25.5 | 3.19 |
26 | 3.24 |
26.5 | 3.28 |
27 | 3.34 |
27.5 | 3.39 |
28 | 3.44 |
28.5 | 3.48 |
29 | 3.53 |
29.5 | 3.56 |
30 | 3.61 |
30.2 | 3.64 |
30.4 | 3.65 |
30.6 | 3.66 |
30.8 | 3.67 |
31 | 3.69 |
31.2 | 3.7 |
31.4 | 3.72 |
31.6 | 3.74 |
31.8 | 3.76 |
32 | 3.77 |
32.2 | 3.79 |
32.4 | 3.8 |
32.6 | 3.82 |
32.8 | 3.83 |
33 | 3.83 |
33.2 | 3.86 |
33.4 | 3.87 |
33.6 | 3.89 |
33.8 | 3.91 |
34 | 3.92 |
34.2 | 3.93 |
34.4 | 3.94 |
34.6 | 3.96 |
34.8 | 3.99 |
35 | 4 |
35.2 | 4.01 |
35.4 | 4.03 |
35.6 | 4.05 |
35.8 | 4.06 |
36 | 4.09 |
36.2 | 4.1 |
36.4 | 4.12 |
36.6 | 4.13 |
36.8 | 4.15 |
37 | 4.17 |
37.2 | 4.19 |
37.4 | 4.21 |
37.6 | 4.23 |
37.8 | 4.25 |
38 | 4.27 |
38.2 | 4.29 |
38.4 | 4.31 |
38.6 | 4.34 |
38.8 | 4.35 |
39 | 4.38 |
39.2 | 4.4 |
39.4 | 4.43 |
39.6 | 4.45 |
39.8 | 4.48 |
40 | 4.5 |
40.2 | 4.54 |
40.4 | 4.57 |
40.6 | 4.58 |
40.8 | 4.62 |
41 | 4.65 |
41.2 | 4.69 |
41.4 | 4.71 |
41.6 | 4.78 |
41.8 | 4.81 |
42 | 4.84 |
42.2 | 4.89 |
42.4 | 4.98 |
42.6 | 5.05 |
42.8 | 5.13 |
43 | 5.2 |
43.2 | 5.28 |
43.4 | 5.46 |
43.6 | 5.57 |
43.8 | 5.81 |
44 | 6.11 |
44.2 | 6.74 |
44.4 | 8.42 |
44.6 | 9.17 |
44.8 | 10.14 |
45 | 10.33 |
45.2 | 10.5 |
45.4 | 10.65 |
45.6 | 10.79 |
45.8 | 10.89 |
46 | 10.92 |
46.2 | 10.98 |
46.4 | 11.05 |
46.6 | 11.12 |
46.8 | 11.16 |
47 | 11.21 |
47.2 | 11.23 |
47.4 | 11.26 |
47.6 | 11.3 |
47.8 | 11.33 |
48 | 11.35 |
48.2 | 11.37 |
48.4 | 11.4 |
48.6 | 11.42 |
48.8 | 11.44 |
49 | 11.46 |
49.2 | 11.48 |
49.4 | 11.5 |
49.6 | 11.51 |
49.8 | 11.53 |
50 | 11.54 |