Chemistry 2210A/B Study Guide - Final Guide: Polar Stratospheric Cloud, Tropospheric Ozone, Fractional Distillation

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21 Dec 2013
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Molecules and bonds absorb at different frequencies of light. Wavelengths shorter than 120 absorbed by o2 and n2. O2 above stratosphere absorbs most uv light from 120-220 (c) O3 absorbs light in 220-290 range (all of c, very little b) Shorter the wavelength, more absorption will not reach earth. Ozone creation and destruction in the stratosphere; the chapman cycle (don"t memo rize equations; just what is happening?) First reaction: o2 2o (absorb uv-c, shortest wavelength, highest energy: above stratosphere ! filters most uvc before reach strato, mostly o. Second reaction: o + o2 o3 + heat: in stratosphere, oxygen mainly molecular. Third: o3 absorbs uva o + o2. Fourth: o3 + o 2o2 (small extent, high ea) Cycle is naturally occurring during daylight hours, and occurs in stratosphere. O3 + x xo + o2. Xo + o o2 + x. X + o3 xo + o2. X" + o3 x"o + o2.

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