CHEM1101 Study Guide - Midterm Guide: The Strongest, Intensive And Extensive Properties, Standard Hydrogen Electrode
Voltaic (Electrochemical) Cells
• I spotaeous redo reatios, eletros are trasferred ad eerg is released.
• That eerg a do ork if the eletros flo through a eteral
device.
• This is a oltai eletroheial ell.
-The oxidation occurs at the anode.
• The redutio ours at the athode gais e-s)
• Whe eletros flo, harges are’t alaed. So, a salt ridge, usuall
a U-shaped tube that contains a salt solution, is used to keep the
charges balanced.
In the cell, electrons leave the anode and flow through the wire to the
cathode.
• Catios are fored i the aode opartet.
• As the eletros reah the athode, atios i solutio are attrated to the o egatie athode.
• The atios gai eletros ad are deposited as metal on the
cathode.
Electromotive Force (emf)
• Water flos spotaeousl oe a i a aterfall.
• Coparal, eletros flo spotaeousl oe a i a redo
reaction, from high to low potential energy.
Electromotive Force (emf)
• The potential difference between the anode and cathode in a cell is called the electromotive force
(emf).
• It is also alled the ell potetial ad is desigated Ecell.
• It is easured i olts V. Oe olt is oe joule per oulo 1 V = 1 J/C.
Standard Reduction Potentials
• Redutio potetials for a eletrodes hae ee
measured and tabulated.
• The alues are opared to the redutio of hdroge as a
standard.
Reduction occurs preferably in the couple with a more
positive standard reduction potential.
Eg: electrochemical couple: Fe3+/Fe+2. Most oxidised species
is written first
Tbale>>: f has a greater chance founder going reaction as
2.87 is higher than say FE which is less positivd thus less
chance of the reaction occiring.
Standard Hydrogen Electrode
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Document Summary
Voltaic (electrochemical) cells: i(cid:374) spo(cid:374)ta(cid:374)eous redo(cid:454) rea(cid:272)tio(cid:374)s, ele(cid:272)tro(cid:374)s are tra(cid:374)sferred a(cid:374)d e(cid:374)erg(cid:455) is released, that e(cid:374)erg(cid:455) (cid:272)a(cid:374) do (cid:449)ork if the ele(cid:272)tro(cid:374)s flo(cid:449) through a(cid:374) e(cid:454)ter(cid:374)al device, this is a (cid:448)oltai(cid:272) (cid:894)ele(cid:272)tro(cid:272)he(cid:373)i(cid:272)al(cid:895) (cid:272)ell. The oxidation occurs at the anode: the redu(cid:272)tio(cid:374) o(cid:272)(cid:272)urs at the (cid:272)athode (cid:894)gai(cid:374)s e-s, whe(cid:374) ele(cid:272)tro(cid:374)s flo(cid:449), (cid:272)harges are(cid:374)"t (cid:271)ala(cid:374)(cid:272)ed. So, a salt (cid:271)ridge, usuall(cid:455) a u-shaped tube that contains a salt solution, is used to keep the charges balanced. Electromotive force (emf: water flo(cid:449)s spo(cid:374)ta(cid:374)eousl(cid:455) o(cid:374)e (cid:449)a(cid:455) i(cid:374) a (cid:449)aterfall, co(cid:373)para(cid:271)l(cid:455), ele(cid:272)tro(cid:374)s flo(cid:449) spo(cid:374)ta(cid:374)eousl(cid:455) o(cid:374)e (cid:449)a(cid:455) i(cid:374) a redo(cid:454) reaction, from high to low potential energy. Electromotive force (emf: the potential difference between the anode and cathode in a cell is called the electromotive force (emf), it is also (cid:272)alled the (cid:272)ell pote(cid:374)tial a(cid:374)d is desig(cid:374)ated ecell, it is (cid:373)easured i(cid:374) (cid:448)olts (cid:894)v(cid:895). O(cid:374)e (cid:448)olt is o(cid:374)e joule per (cid:272)oulo(cid:373)(cid:271) (cid:894)1 v = 1 j/c(cid:895).