CHM1011 Study Guide - Quiz Guide: Solution, Enthalpy

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Internal energy (u): sum of all energy types of all particles in a sample of matter. Enthalpy (h): heat absorbed or evolved by a chemical system determined by measuring temperature change: release of heat energy=exothermic reaction- h<0, absorption of heat energy=endothermic reaction- h>0, h= u + p v. Entropy (s): measure of disorder- the number of ways energy is distributed throughout a chemical system: ssurr= - hsys/t, ssys = hsys/t. Gibbs" free e(cid:374)ergy (cid:894)g(cid:895): g= h ts, where t=temperature. Have unique values once the state of the system is defined. U depends only on the net change in state functions. Depend on the way that the change occurs. Have no meaning when no change is occurring. Both endothermic and exothermic reactions may be spontaneous. Spontaneous reactions involve a change in the degree of disorder. Can be observed by an increase in number of moles. Increases for dissolved substances when compared to pure substance.

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