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Midterm

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Department
Chemistry
Course
CHEM 203
Professor
William C.Galley
Semester
Fall

Description
Chem203SurveyofPhysicalChemistryTableofContentsCourseoutline1Lecture13Lecture28Lecture313Lecture418Lecture522Lecture627Lecture734Lecture845Lecture9FormationandCombustionReactions45Enthalpyofformation45Analogy46HydrolysisofATP47HessLaw47ResonanceStabilization48Lecture10TemperatureDependenceofEandHforPhaseChanges50TheVaporizationofHO502OverLongTRanges51TheDeterminationofChangesinStateFunctionfromHeatMeasurements52GasExpansion52IsothermalExpansion52Lecture11Entropy53Courseoutline Introductiontobondmakingandbreaking Bondenergies Combustionandhydrolysisreactions ATPhydrolysis MolecularEnergieso Types Translational Rotational Vibrational Electrical2o Temperaturedependenceofaveragemolecularenergieso Thermalandbondingenergieso Quantizationo Covalentandintermolecularinteractions The1stLawofThermodynamicso Systemso Surroundingso Statefunctionso Processes Reversible Irreversibleo Heatworko Energyenthalpychangeso CCpvo Thermochemistryo Isothermaladiabaticcalorimetryo HessLawo Temperatureheatsofreactionso Molecularenergychangesinreactionso Calculationofbondenthalpyenergies Entropyandthe2ndLawo Entropyo Entropychangeso Carnotcycleo Temperatureentropyo Pressureentropyo Sforphasechangeso Absoluteentropieso Sforreactionso Sforthesystemsurroundingstheuniverseo Gibbsenergychangeso Maximumworko DependenceofGonpartialpressuresconcentrationsoo EquilibriumconstantsGo TdependenceofKVantHoffplots BiophysicalApplicationso Bioenergeticsmetabolismo Coupledprocesseso Diffusionactivetransporto Hydrophobicityo Thermodynamicsofproteinstabilityo Bindingplotsandbindingconstantso Multipleequilibria ChemicalKineticso Review Ratesordersofreactions3 Rateconstantso Halflivessto Pseudozero1orderprocesseso Initialrateso Cotanalysiso Elementaryreactionso Reverseo Parallelconsecutivereactionso Steadystateapproximationo Reactionmechanismso Predictingorderfrommodelso Enzymecatalyzedreactionso TdependenceofKo ArrheniusTransitionStatetheorieso Activationenergyentropyo CatalysisLecture1 Howwhydolivingorganismsinteractwiththeenvironmento Accumulategrowo Formcomplexorderedstructureso Doworko Runfasto Sing Exampleo Nitroglycerinhasweakbonds Bondsmadenoinputofenergy Bondsbrokeninputofenergyisrequired Energyrichphosphateso Misleading Notsomespecialkindofbondthatreleasesenergywhenbroken Energymustbeexpendedtobreakabond
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