CHEM 282- Final Exam Guide - Comprehensive Notes for the exam ( 24 pages long!)

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The boiling points of ethers are sort of comparable to the boiling points of hydrocarbons of the same molecular weight. The molecules of ethers cannot hydrogen bond to each other. Ethers cannot hydrogen bond to each other , but they can hydrogen bond to water physical properties o(cid:304) alcohols. The molecules of alcohols can hydrogen-bond to each other. Both alcohols and ethers can hydrogen bond to water and have similar solubilities in water. Diethyl ether and 1-butanol have solubilities of about 8 g per. This is a reversible reaction with markovnikov regioselectivity. The halide component of hx bonds preferentially at the more highly substituted carbon , whereas the hydrogen prefers the carbon which already contains more hydrogens. Halide ion goes to the carbon with more r (more substituted) Hydrogen attacks the carbon that has more h (cid:560)h+(cid:561) the rich (cid:305)et richer. This is a markovnikov addition which occurs without rearrangement. This addition reaction occurs with anti-markovnikov regiochemistry and syn stereochemistry.

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