CHEM164 Study Guide - Midterm Guide: Benzene, Nucleophilic Addition, Nitration
12 Jun 2015
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Nuclear magnetic resonance (nmr) spectroscopy: introduction to nmr spectroscopy. Chemical shifts: shielding and deshielding, qualitative analysis: using elementary 1h nmr spectroscopy for structural analysis. Signal integration: peak area gives the number of protons. Chapter 11 structure and synthesis of alcohols ( review from c261/164) Assigned problems: 11. 1 11. 29 (inclusive), 11. 30 11. 46, 11. 48: alcohol oxidation: synthesis of carbonyl compounds, conversions of alcohols to other functionality. Synthesis and cleavage of ethers: epoxidation of alkenes and epoxide-opening reactions. Assigned problems: 12. 1, 12. 2, 12. 4 (parts 1, 2 only), 12. 5a,b, 12. 6, 12. 9 12. 23, 12. 25, 12. 26, 12. 28, 12. 29, 12. 33-12. 36, 12. 37, 12. 38 (some parts are pretty hard! 12. 43, 12. 45 (good problem), 12. 47, 12. 48a-d,f-h, 12. 49 12. 56, 12. 58 12. 60. Chapter 14 ethers and epoxides: synthesis and cleavage of ethers, epoxidation of alkenes and epoxide-opening reactions. Assigned problems: 14. 1 14. 2, 14. 4 14. 5, 14. 7 14. 9 (williamson part only), 14. 13 14. 14(not e), Chemistry 263 2015 (stryker: introduction to conjugation. The allyl system: resonance theory (review) and molecular orbital (mo) description.
