CHM 1321 Study Guide - Final Guide: Reagent, Heterocyclic Compound, Iodine Monochloride

• School: University of Ottawa
• Department: Chemistry
• Course: CHM 1321
• Professor: William Ogilvie

Document Summary

Markovnikov"s rule reaction proceeds through the most stable carbocation; this leads to the major product. Oxymerculation: reaction to add h2o across a double bond, mild rxn conditions to avoid rearrangement of the double bond, step 1: double bond reacts with hg(oac)2 & h2o to create a single bonded chain with. Regioselection: regioisomers: heavy component goes on either region of the molecule, markovnikov product: the heavy component of the water (ex. Oh) goes onto the most substituted carbon: non-markovnikov product: the heavy component of the water (ex. Bromonium ions opened by other nucleophiles for a compound with a double bond reacting with br2 and water, double bond breaks and. Nomenclature: prefix + benzene (c6h6, ex. bromobenzene, hydroxybenzene, many simple aromatics have trivial names, ex. Ph = phenyl represents benzene ring with an r group attached: ph-oh is phenol, ph-och3 is anisole, ph-cho is benzaldehyde, ph-nh2 is aniline, ph-ch3 is toluene, ph-co2h is benzoic acid.