CHM247H1 : NMR and IR.pdf

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24 Apr 2014

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Identification of organic compounds: nmr and ir spectroscopy. Both nmr (nuclear magnetic resonance) and ir (infrared) spectroscopy rely on electromagnetic radiation. Ir spectroscopy; stretching and bending energies of bonds in specific functional groups. Use detectors to figure out wavelengths ( ), what the absorbance of those wavelengths are, etc. Electromagnetic radiation acts as both a particle and a wave; propagates as a wave in discrete quantities of energy (quanta: as a particle, one unit is a photon. A photon contains a discrete amount of energy, called a quantum: as a wave, characteristic length ( ; measured crest-to-crest or trough-to-trough) and frequency ( ; reported in cycles per second, s-1, also called hertz, hz) Frequency = how many waves will pass a given point per second. Both the wavelength and frequency ( and ) of a wave tell us its energy. E = h = hc( c = 3. 0x108m/s (speed of light: h = planck"s constant, 1. 58x10-34cal s or 6. 626x10-34j s.

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LIGHT LAB SPRING 2018 CHEM 1430 Ill. Quantization of Electromagnetic Radiation In 1894, the German physidist, Max Plank, was working for a utility company to maximize visible light output from incandescent lamps using minimum power. Based on theoretical considerations, Planck postulated that electromagnetic energy could only be emitted at discrete values, rather than the continuum of predicted by classical physics, as multiples of the frequency of the radiation. Planck's Postulate took the mathematical form: EÂ·hv where the energy emitted, in Joules, is the product of a constant, h, known as Planck's Constant, and the frequency of the radiation, v. Planck's Postulate was experimentally verified and h found to have the value of 6.626 x 1034 Js(Joule seconds). The idea that electromagnetic radiation energy had specific frequency dependent energy was termed a "quantum of action," a distressing finding for the dlassically trained Planck. Despite his objections, Planck adopted this quantization of energy as a last resort to reconcile experiment with theory. This discovery set the stage for the early understanding of atomic structure, led to the term "photon" to describe the packet of energy carried by light waves, led to an understanding of the photoelectric effect, eventually leading to the development of general quantum theory Planck's Relationship, in combination with the tight equation, c the energy of a photon from frequency or wavelength. Î» w, allow expressions to be written to calculate ACTIVITY 4: QUANTIZATION OF THE ENERGY OF RADIATION To practice cakculations with Planck's Relationship, complete the following table, showing work with units in the right mest column, Convert given frequency to energy or given wavelength to energy. Take the value for Planck's Constant, h, to be 6.626 x 10"Js, show a calculation string include dimensions, reporting the final value to the proper number of significant figures Spectral Region Wavelength Frequency Energy in J/photon Show Calculation String Î» in meters v in s or cps X-ray 6.0 x 10"m Blue light 4.5 x 10m Infrared 4.1 x 10" cps Microwave 7.3 x 101 cps Radio Wave 3.0x 10 m IV. Bohr's Quantum Model for the Hydrogen Atom Ernest Rutherford's Gold Foil Experiment of 1911 demonstrated the nuclear structure of the atom. Questions remained as to how electrons were arranged in the atom. The most common belief called for the negatively charged the late 19h century recognized a particle (an electron) traveling around a body (the positively charged nucleus) would continuously radiate energy, slowing over time, eventually falling into the nucleus. Matter would collapse. Page 8 of 12

CHM247H1 : NMR and IR.pdf

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