CHEM 213 Study Guide - Midterm Guide: Epoxide, Hydrogen Bond, Sodium Amide

• School: SUNY Geneseo
• Department: Chemistry
• Course: CHEM 213
• Professor: charlebois Amber

Document Summary

Fisher projections: horizontal is coming towards you, middle is on the plane and top/bottom is going out. The more oh, the higher the bp cause hydrogen bonding forces. Secondary halogens primary alcohol: bulky base to pull an x off and form an alkene ex. (ch3)3oh, adding an alcohol acid catalyzed, hydroboration, oxymercuration-demercuration, These add either markovnikov or non-mark. need to look at substituents attached directly to the double bonded cs: tertiary carbocations are most stable. Primary oh with hbr one stereochem. Secondary oh with hbr two stereochem. Epoxidation: start with z cis, start with e trans, breaking. Nanh2 and alcohols: nh2 rips off an h from the alcohol, and na will associate with the neg charged o. Sunday, february 12, 2017: this is helpful for making ethers. Williamson synthesis: start with an x. Allylic position = one away from double bond. Vinylic position = on the double bond.