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Final

01:160:161 Chapter Notes - Chapter 23: Structural Isomer, 3Cr Melbourne, DenticityExam


Department
Chemistry
Course Code
01:160:161
Professor
Asbed Vassilia
Study Guide
Final

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CHAPTERS 23
COORDINATION CHEMISTRY
Problems to prepare students for hourly exam III.
COORDINATION COMPOUNDS
E. Tavss, PhD
3/22/12

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CHAPTER 22 - TRANSITION METALS AND COORDINATION CHEMISTRY
10 Chem 162-2011 Final exam
Chapter 22 – Transition Metals and Coordination Chemistry
Coordination compounds
What is the correct name for the complex ion [Fe(C2O4)Cl4]3-?
A. Tetrachlorooxalatoiron(III)
B. Tetrachlorooxalatoferrate(III)
C. Tetrakis(oxalatochloro)ferrate(II)
D. Irontetrachlorooxalate(III)
E. Chlorooxalatoferrate(III)
14 Chem 162-2011 Final exam
Chapter 22 – Transition Metals and Coordination Chemistry
Coordination compounds
Which of the following compounds exhibit geometric isomers?
I. Pt(NH3)2Cl2 (square planar)
II. [Co(NH3)6]Cl3
III. [Ni(NH3)4(NO2)2]
IV. K2[CoCl4] (tetrahedral)
A. I and III
B. I only
C. II only
D. I and IV
E. III and IV

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3
49 Chem 162-2011 Final exam
Chapter 22 – Transition Metals and Coordination Chemistry
Coordination compounds
What is the coordination number of copper in the complex [Cu(en)2(H2O)2]2+?
A. 3
B. 2
C. 5
D. 4
E. 6
Chem 162-2011 Exam III + Answers
Chapter 22 - Transition Metals and Coordination Chemistry
Coordination Compounds
1. Which of the following is called a chelating ligand?
A. NO2-
B. CN-
C. CH3CH2CH2NH2
D. -OOCCOO-
E. NH3
Chem 162-2011 Exam III + Answers
Chapter 22 - Transition Metals and Coordination Chemistry
Coordination Compounds
3. What is the correct formula for the diamminetetracyanocobaltate(III) ion?
A. [Co(CN)(NH3)]2+
B. [Co(CN)4(NH3)2]3+
C. [Co(CN)4(NH3)2]
D. [Co(CN)4(NH3)2]+
E. [Co(CN)4(NH3)2]-
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