GEOG 2210 Chapter : GEOG 2210 Chpt 4 Summary

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11 Feb 2012

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Game theory a form of applied mathematics used to model and predict people"s behavior in strategic situations where people"s choices are predicted on predicting the behavior of others. Institutions rules/ norms governing collective action, especially referring to rules governing common-property environmental resources, like rivers, oceans, or the atmosphere. Prisoner"s dilemma an allegorical description of a game-theoretical situation in which multiple individuals making decisions in pursuit of their own interests tend to create collective outcomes that are non-optimal for everyone. Social darwinism theory to explain social phenomena; as individuals are viewed as naturally and inherently competitive and selfish beings, social darwinism typically rationalizes war, poverty, and hierarchically stratified social systems. Why are global emissions so hard to control: one argument is that carbon does not stay put. With every activity (ie. driving a car, burning a log, etc. ) carbon is released and enters the atmosphere.

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Vapor cycles
5EM - Thermodynamics
September 2010
1 The T-S diagram
The temperature-entropy diagram is an alternative to the well knownpressure-
volume diagram. Before using it to analyze different vapor cycles,we need
to understand it properly.
1. Plot the following transformations for ideal gases in a T-Sdiagram
(a) Isothermal expansion
(b) Isobaric expansion
(c) Isometric heating
(d) Reversible adiabatic expansion
(e) Irreversible adiabatic expansion
2. Repeat the last question, but this time do it for a realsubstance,
starting in the compressed liquid1 region and ending in thesuperheated
region, when possible. Indicate the boundaries of eachregion.
3. We know that under certain circumstances the area under theplot
in a P-V diagram represents the work performed during theprocess.
What does it represent in this case? Under what assumptions isyour
answer true? Compare examples 6.1 and 6.2.
2 Thermal machines
We understand by thermal machine a device capable of transformingther-
mal energy (heat) into mechanical energy (work). We already knowthat
these machines have a limited efficiency which, in the two-sourcesmodel, is
obtained by Carnotâs cycle.
(Compressed liquid is sometimes also called subcooled liquid)
2.1 Carnot cycle
This cycle, although efficient, is impractical. To begin with, theextreme
temperatures of the cycle should be within the sources temperaturesfor a
finite heat flow to exist.
1. Given the temperature of the sources, draw the cycle accordingto the
named limitation.
2. Show that this leads to lower efficiency than the theoreticallimit.
3. Assume that heat flow from/to the sources is proportional to thetem-
perature difference between them and the working fluid, anddemon-
strate that a higher power output is related to a decreasedefficiency.
2.2 Rankine cycle
Out of the several practical possibilities, Rankine cycle and itsvariations is
widely used, especially for electric power generation.
1. Draw the basic cycle in a T-S diagram and explain it.
2. What does the efficiency of the cycle depend on? Comparewith
Carnotâs.
3. What are the differences between the ideal cycle and the realone?
4. Describe how it is modified by superheating and/or reheating.Explain
te benefits.
2.3 Problems
After answering the previous questions solve the followingexercises from the
book: 8.2, 8.4, 8.5, 8.13, 8.19, 8.20
3 Frigorific machines
3.1 Reverse Carnot cycle
We have already studied Carnot cycle in detail as the ideal thermalmachine.
Now we will take is as the starting point to understand thecharacteristics
of frigorific machines.
1. Draw the ideal cycle in a T-S diagram and explain it.
2. Show that this cycle has a theoretical efficiency Ã =Tcold/Thot-Tcold
3. What are the difficulties in implementing such cycle in actualdevices?
3.2 Actual refrigerators
1. Why is the turbine replaced by an expansion valve in mostcases?
2. Plot the actual cycle and explain the differences with the idealcase.
3. How do cascade and multistage systems improve the performanceof
the refrigerator?
4. What aspects are important in the choice of a refrigerant fluid?Justify
3.3 Problems
After answering the previous questions solve the followingexercises from the
book: 10.2 10.7, 10.8, 10.9, 10.22, 10.23 10.1D

3. 3 Stratosphere-troposphere exchange

The rate of exchange of air between the troposphere and thestratosphere is critical for determining the potential of variouspollutants emitted from the surface to reach the stratosphere andaffect the stratospheric ozone layer. One of the first estimates ofthis rate was made in the 1960s using measurements of strontium-90(90Sr) in the stratosphere. Strontium-90 is a radioactive isotope(half-life 28 years) produced in nuclear explosions. It has nonatural sources. Large amounts of 90Sr were injected into thestratosphere in the 1950s by above-ground nuclear tests. Thesetests were banned by international treaty in 1962. Following thetest ban the stratospheric concentrations of 90Sr began to decreaseas 90Sr was transferred to the troposphere. In the troposphere,90Sr is removed by wet deposition with a lifetime of 10 days (bycontrast there is no rain, and hence no wet deposition, in thestratosphere). An intensive stratospheric measurement network wasoperated in the 1960s to monitor the decay of 90Sr in thestratosphere. We interpret these observations here using a 2-boxmodel for stratosphere-troposphere exchange with transfer rateconstants kTS and kST (yr-1) between the tropospheric andstratospheric reservoirs. The reservoirs are assumed to beindividually well-mixed.

Let mS and mT represent the masses of 90Sr in the stratosphere andin the troposphere respectively. Observations of the decrease inthe stratospheric inventory for the period 1963-1967 can be fittedto an exponential mS(t) = mS(0)exp(-kt) where k = 0.77 yr-1.

1. Write mass balance equations for mS and mT in the 1963-1967period.

2. Assuming that transfer of 90Sr from the troposphere to thestratosphere is negligible (we will verify this assumption later),show that the residence time of air in the stratosphere is tS =1/kST = 1.3 years.

3. Let m'T and m'S represent the total masses of air in thetroposphere and the stratosphere, respectively. Show that theresidence time of air in the troposphere is tT = tS (m'T/m'S) = 7.4years. Conclude as to the validity of your assumption in question2.

4. Hydrochlorofluorocarbons (HCFCs) have been adopted asreplacement products for the chlorofluorocarbons (CFCs), which werebanned by the Montreal protocol because of their harmful effect onthe ozone layer. In contrast to the CFCs, the HCFCs can be oxidizedin the troposphere, and the oxidation products washed out byprecipitation, so that most of the HCFCs do not penetrate into thestratosphere to destroy ozone. Two common HCFCs have trade namesHCFC-123 and HCFC-124; their lifetimes against oxidation in thetroposphere are 1.4 years and 5.9 years, respectively. There are noother sinks for these species in the troposphere. Using our 2-boxmodel, determine what fractions of the emitted HCFC-123 andHCFC-124 penetrate the stratosphere.

Huygens' principle (first described by the Dutch scientist Christiaan Huygens in 1678) uses geometry to determine the shape of a wavefront at a time t, given some initial wavefront at an earlier time. This can be constructed by imagining that the initial wavefront is a source of wavelets that propagate from each point at the speed of light. From this principle, one can determine the angles of reflection and refraction by considering the speed of light at each point on the wavefront. In this problem, we will explore some of these concepts.

Part A

First, let's look at a plane wave that is incident on a flat piece of material with an index of refraction n. Part of the light is transmitted through the material and part of it is reflected. For the moment, let's just look at the part that is transmitted. At time t=0, the wavefront is a distance d away from the surface of the material. At time t=t₁, the wavefront is at the position of the material interface. Use the Huygens' principle to determine how far into the material (d') the wavefront has propagated by time t=2t₁.

Express your answer in terms of the variables n, t₁, and the speed of light in a vacuum c.

Note that there would be no change in the direction of the wavefront at any point because the wavefront encountered the material interface at the same time at all points. Thus, all of the individual wavefronts all propagated at the same speed, thereby maintaining the flat wavefront.

Now, instead of having a flat wavefront propagating normal to the material interface, we have a flat wavefront propagating toward the material at an angle of 55° to the axis perpendicular to the material interface. In this part, we will look at the relative positions of a few points—A, B, and C—on the wavefront to illustrate Huygens' principle. (Intro 1 figure) Point C touches the vacuum/material interface at time t=0 whereas point B is a distance d and point A is a distance 2d away from the interface.

Part B

What is the time t_B it will take for point B of the wavefront to encounter the vacuum/material interface?

Express your answer numerically to two decimal places in units of t₁ (the time it takes light to travel a distance d in a vacuum).

It should be noted that the accuracy of the method increases the smaller the distance is before making a new wavefront and redoing the wavelets. If you tried to just draw a large wavelet from point B, then it would hit the surface after only traveling a distance d. This large wavelet would make it difficult to visualize how to add up all of the other wavelets to make a coherent wavefront. As a result, one should just draw a line perpendicular to the wavefront at point B until it hits the surface, at which point the wavelets will change owing to the new index of refraction.

Part C

How far did point C go into the material interface in the time t=t_B that it took for point B to get to the interface? For this part we are looking for the distance traversed by the point C in the material (d_C).

Give your answer in terms of the time t_B, c, and n.

Part D

What is the new angle θ at which point C of the wavefront is propagating (relative to a line perpendicular to the vacuum/material interface)? Try to use the fact that you have a spherical wavefront propagating from t=0 at the point where C met the vacuum/material interface until time t_B when the wavefront at point B reached the interface.

Express your answer in terms of inverse trigonometric functions and n.

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GEOG 2210 Chapter : GEOG 2210 Chpt 4 Summary

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