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problem set 7 answer

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Department
Chemistry
Course
CHEM 313
Professor
All Professors
Semester
Fall

Description
Chem 313 Problem Set #7, 2010 1. The net reaction of -ketoglutamate transaminase is shown below. Fill in the unknown products. Net reaction: O O AKG-transaminase O PLP + ? ? + HO OH OH NH2 NH 2 2. The formation of amino-cycloproyl carboxylate (ACC) is an important step in plant metabolism, leading to the formation of ethylene. A PLP-dependent enzyme –ACC-synthase - performs this reaction with S-adenosyl methionine (SAM) as the substrate. Propose a mechanism for this reaction. (Plant Physiol. 1989, 1036). A A O ACC-synthase O OH PLP OH CO H 2 OH
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