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Chapter 6: Ionic Reactions
Organic Halides
•


•  
 ! "
Nucleophilic Substitution Reactions
•#$%&'%#$&'
•()

•*&+  )

Nucleophiles and Leaving Groups
•#,)-)

•* +  
))-)
))+,
Kinetics of a Nucleophilic Substituion Reaction: An Sn2 Reaction
•. +  
))
•/ 
+
•%"0101
•*)
A Mechanism for the Sn2 Reaction
•*)
,++)
•()+
)

•*. 

)

•*. +
,
Transition State Theory: Free-Energy Diagrams
•23 )∆'°
)
•2)∆'°
)
•∆'°"%*45
•627
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333
o%+
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
o62%∆'°

•8)+∆'°9∆'
•8)+∆'°:∆'
•(;<°
,
•,",<∆'=%*+,<+5

•()∆'3
)∆'
The Stereochemistry of Sn2 Reactions
•*, 
)-
;><°),
•#). 
)
•/+)
)

•. )
The Reaction of tert-Butyl Chloride with Hydroxide Ion: An Sn1 Reaction
•%.;%",01

•%7.,
 + )

A Mechanism for the Sn1 Reaction
•*,
•7,!
)
•*)!-

Carbocations
•
•*-3
)
•*+ 

•*),
))
o*+
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