GGR107H1 Chapter Notes -Traidcraft, Organic Food, Food Systems

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27 May 2012

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6. 4 alternative geographies of food: concepts and case studies. Alternative food networks: respond to questions about food. Consumers are often interested in slow food and local foods to help with the issue. Conversions about organic foods and fair trade share ethical and ecological possibilities. Fair trade started about 50 years ago when oxfam and traidcraft realized the importance of consumers. Fair trade is available in most european supermarkets. Rapid growth and popularity for fair trade items: short food supply chains (sfscs): sfscs is food reach the final consumer through an embedded chain. Products reach the consumer without them knowing about the processes that occur: social embeddedness: propagates the economic behaviour by social relations. Social interaction with the consumer can make a difference in the food they buy: the turn to quality: notion of higher quality foods. Defensive localism: local foods can turn into quality foods. In europe they attempt to link product and place.

Related Questions

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1.Energetics of diatomic systems II.

An approximate expression for the potential energy of two

ions as a function of their separation is

= âke2r+br9 (1)

The first term is the usual Coulomb interaction,while the second term is introduced to account for

the repulsive effect of the two ions at smalldistances.

(a) Find b as a function of the equilibrium

spacing ro. (b) Calculate the potentialenergy of KCl at its equilibrium spacing (ro =0.279 nm)

2.Energetics of diatomic systems III. An expression forthe potential energy of two neutral atoms

as a function of their separation

r is given by the Morse potential,

= Poh1 â eâa(râro)i2 (2)

(a)

Show that ro is the atomic spacing and Po the dissociation energy.(b) Calculate the force

constant for small oscillations about r=ro.

3.Crystal lattice energy. Consider a one-dimensionalchain of alternating positive and negative

ions. Show that the potential energy associatedwith one of the ions and its interactions with the

rest of this hypothetical crystal is

(r) = âkee2r(4)

where the Madelung constant is

=2 ln 2 and r is the interionic spacing.

Vapor cycles
5EM - Thermodynamics
September 2010
1 The T-S diagram
The temperature-entropy diagram is an alternative to the well knownpressure-
volume diagram. Before using it to analyze different vapor cycles,we need
to understand it properly.
1. Plot the following transformations for ideal gases in a T-Sdiagram
(a) Isothermal expansion
(b) Isobaric expansion
(c) Isometric heating
(d) Reversible adiabatic expansion
(e) Irreversible adiabatic expansion
2. Repeat the last question, but this time do it for a realsubstance,
starting in the compressed liquid1 region and ending in thesuperheated
region, when possible. Indicate the boundaries of eachregion.
3. We know that under certain circumstances the area under theplot
in a P-V diagram represents the work performed during theprocess.
What does it represent in this case? Under what assumptions isyour
answer true? Compare examples 6.1 and 6.2.
2 Thermal machines
We understand by thermal machine a device capable of transformingther-
mal energy (heat) into mechanical energy (work). We already knowthat
these machines have a limited efficiency which, in the two-sourcesmodel, is
obtained by Carnotâs cycle.
(Compressed liquid is sometimes also called subcooled liquid)
2.1 Carnot cycle
This cycle, although efficient, is impractical. To begin with, theextreme
temperatures of the cycle should be within the sources temperaturesfor a
finite heat flow to exist.
1. Given the temperature of the sources, draw the cycle accordingto the
named limitation.
2. Show that this leads to lower efficiency than the theoreticallimit.
3. Assume that heat flow from/to the sources is proportional to thetem-
perature difference between them and the working fluid, anddemon-
strate that a higher power output is related to a decreasedefficiency.
2.2 Rankine cycle
Out of the several practical possibilities, Rankine cycle and itsvariations is
widely used, especially for electric power generation.
1. Draw the basic cycle in a T-S diagram and explain it.
2. What does the efficiency of the cycle depend on? Comparewith
Carnotâs.
3. What are the differences between the ideal cycle and the realone?
4. Describe how it is modified by superheating and/or reheating.Explain
te benefits.
2.3 Problems
After answering the previous questions solve the followingexercises from the
book: 8.2, 8.4, 8.5, 8.13, 8.19, 8.20
3 Frigorific machines
3.1 Reverse Carnot cycle
We have already studied Carnot cycle in detail as the ideal thermalmachine.
Now we will take is as the starting point to understand thecharacteristics
of frigorific machines.
1. Draw the ideal cycle in a T-S diagram and explain it.
2. Show that this cycle has a theoretical efficiency Ã =Tcold/Thot-Tcold
3. What are the difficulties in implementing such cycle in actualdevices?
3.2 Actual refrigerators
1. Why is the turbine replaced by an expansion valve in mostcases?
2. Plot the actual cycle and explain the differences with the idealcase.
3. How do cascade and multistage systems improve the performanceof
the refrigerator?
4. What aspects are important in the choice of a refrigerant fluid?Justify
3.3 Problems
After answering the previous questions solve the followingexercises from the
book: 10.2 10.7, 10.8, 10.9, 10.22, 10.23 10.1D

3. 3 Stratosphere-troposphere exchange

The rate of exchange of air between the troposphere and thestratosphere is critical for determining the potential of variouspollutants emitted from the surface to reach the stratosphere andaffect the stratospheric ozone layer. One of the first estimates ofthis rate was made in the 1960s using measurements of strontium-90(90Sr) in the stratosphere. Strontium-90 is a radioactive isotope(half-life 28 years) produced in nuclear explosions. It has nonatural sources. Large amounts of 90Sr were injected into thestratosphere in the 1950s by above-ground nuclear tests. Thesetests were banned by international treaty in 1962. Following thetest ban the stratospheric concentrations of 90Sr began to decreaseas 90Sr was transferred to the troposphere. In the troposphere,90Sr is removed by wet deposition with a lifetime of 10 days (bycontrast there is no rain, and hence no wet deposition, in thestratosphere). An intensive stratospheric measurement network wasoperated in the 1960s to monitor the decay of 90Sr in thestratosphere. We interpret these observations here using a 2-boxmodel for stratosphere-troposphere exchange with transfer rateconstants kTS and kST (yr-1) between the tropospheric andstratospheric reservoirs. The reservoirs are assumed to beindividually well-mixed.

Let mS and mT represent the masses of 90Sr in the stratosphere andin the troposphere respectively. Observations of the decrease inthe stratospheric inventory for the period 1963-1967 can be fittedto an exponential mS(t) = mS(0)exp(-kt) where k = 0.77 yr-1.

1. Write mass balance equations for mS and mT in the 1963-1967period.

2. Assuming that transfer of 90Sr from the troposphere to thestratosphere is negligible (we will verify this assumption later),show that the residence time of air in the stratosphere is tS =1/kST = 1.3 years.

3. Let m'T and m'S represent the total masses of air in thetroposphere and the stratosphere, respectively. Show that theresidence time of air in the troposphere is tT = tS (m'T/m'S) = 7.4years. Conclude as to the validity of your assumption in question2.

4. Hydrochlorofluorocarbons (HCFCs) have been adopted asreplacement products for the chlorofluorocarbons (CFCs), which werebanned by the Montreal protocol because of their harmful effect onthe ozone layer. In contrast to the CFCs, the HCFCs can be oxidizedin the troposphere, and the oxidation products washed out byprecipitation, so that most of the HCFCs do not penetrate into thestratosphere to destroy ozone. Two common HCFCs have trade namesHCFC-123 and HCFC-124; their lifetimes against oxidation in thetroposphere are 1.4 years and 5.9 years, respectively. There are noother sinks for these species in the troposphere. Using our 2-boxmodel, determine what fractions of the emitted HCFC-123 andHCFC-124 penetrate the stratosphere.

GGR107H1 Chapter Notes -Traidcraft, Organic Food, Food Systems

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