Chemistry 1027A/B Chapter Notes - Chapter 13: Trigonal Planar Molecular Geometry, Pi Bond, Orbital Hybridisation

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Functional group of aldehyde: carbonyl group bonded to a hydrogen. Functional group of ketone: carbonyl group bonded to two carbon atoms. Longest chain of carbon atoms that contains functional group. Aldehyde: change suffix e to al, numbering must start with group at carbon 1, unsaturated aldehyde. Presence of carbon-carbon double bond is indicated by infix en: carbaldehyde. Number atom of ring bearing the aldehyde group as number 1: retain common names. Ketone: selecting longest chain that contains carbonyl group, change suffix from e to one, number parent chain from direction carbonyl carbon the smallest number. Compounds with two or more functional groups may be necessary to name carbonyl group as oxo. Precedence order: carboxyl, aldehyde, ketone, alcohol, amino, sufhydryl. Aldehyde: derived from common name of corresponding carboxylic acid, dropping acid and changing suffix ic or oic to aldehyde. Ketone: derived by naming each alkyl group or aryl group bonded to carbonyl group as a separate word, followed by ketone.

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