CHE 101 Chapter Notes - Chapter 2: Hydrogenation, Halohydrin, Hydroxylation

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3 Feb 2021
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Open chain saturated hydrocarbon with general formula (c n h 2n+2 ). All the c atoms are single bonded i. e. sp 3 hybridised. Conformations are the different arrangement of atoms that can be converted into one another by rotation about single bonds. Eclipsed conformation: h atoms on two adjacent carbon atoms are closest to each other i. e. dihedral angle is 0. Staggered conformation: h atoms on two adjacent carbon atoms are farthest to each other i. e. dihedral angle is 60. Rx + zn: + h + rh + zn 2+ + x - 4rx + lialh 4 4rh + lix + alx 3 (x f) Rx + (n - c 4 h 9 ) 3 snh r-h + (n - c 4 h 9 ) 3 snx. Decarboxylation of a mixture of the sodium salt of a carboxylic acid: 2 rcook + 2h 2 o r-r + 2co 2 + h 2 + 2koh.

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