CHEM 140C Chapter Notes - Chapter 19: Hydrolysis, Stereochemistry, .Gg
15 Jan 2018
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Twositesofprotonation destabilized electron by z withdrawing protonation by strong acids takes place on carbonyl oxygen not hydrogen oxygen carbonyl no resonance stabilization resonance stabilization ( all basicityon carboxylic acid is in double bonded. +00 oxidation of bonds increasing # to carbon of. Stops at stops at aldehyde present so presence water of. # brag # ngtrnfey organolithinms should be thought stronger. K got ftp. #ycyanohydri think ofgrignard reagents like a salt. Organolithiumsact k 0 - have carbonyl aldehydes stereochemistry aqacidorbase stereochemistry displacement deformation ofassalts. Making have acidic sensitive to stevie invasion of. D comes acid , reduction workup to alcohol carboxylic. Br long chain carboxylic acids soap , fatlfattyacids. ; long straight chain hn branched carboxylic acids btwn. Carbons in length ( even may have cisor trans alkenes in structure. Saturated ( cib ) fatty acid ( no double bonds. 1 solid ) olive oil glycerol glycerol ( liquid )
